Electrical Arc - Wikimedia Commons

Electrical Arc - Wikimedia Commons

Electrical Arc Contents 1 2 3 4 5 Electric arc 1 1.1 History . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ...

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Electrical Arc

Contents 1

2

3

4

5

Electric arc

1

1.1

History . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

1

1.2

Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

1

1.3

Uses . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

2

1.4

Undesired arcing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

3

1.5

Arc suppression . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

4

1.6

See also . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

4

1.7

References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

4

1.8

External links . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

4

Vacuum arc

5

2.1

References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

5

2.2

See also . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

5

Cathodic arc deposition

6

3.1

History . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

6

3.2

Process . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

6

3.3

Equipment design . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

6

3.4

Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

7

3.5

See also . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

7

3.6

References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

8

Glow discharge

9

4.1

Basic operating mechanism . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

9

4.2

Use in analytical chemistry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

10

4.3

Powering modes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

11

4.4

Types . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

11

4.5

Application to analog computing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

11

4.6

See also . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

11

4.7

References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

11

4.8

Further reading . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

12

Fluorescent lamp

13

5.1

14

History . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i

ii

CONTENTS 5.1.1

Physical discoveries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

14

5.1.2

Early discharge lamps . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

14

5.1.3

Neon lamps . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

16

5.1.4

Commercialization of fluorescent lamps . . . . . . . . . . . . . . . . . . . . . . . . . . .

16

Principles of operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

17

5.2.1

Construction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

17

5.2.2

Electrical aspects of operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

18

5.2.3

Effect of temperature . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

19

5.2.4

Losses . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

19

5.2.5

Cold cathode lamps . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

20

5.2.6

Starting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

20

5.2.7

End of life . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

24

Phosphors and the spectrum of emitted light . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

25

5.3.1

Color temperature . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

26

5.3.2

Color rendering index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

26

5.3.3

Phosphor composition . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

27

5.4

Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

27

5.5

Advantages . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

27

5.5.1

Luminous efficacy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

27

5.5.2

Life . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

27

5.5.3

Lower luminance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

27

5.5.4

Lower heat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

27

Disadvantages . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

28

5.6.1

Frequent switching . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

28

5.6.2

Health and safety issues . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

28

5.6.3

Ultraviolet emission . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

28

5.6.4

Ballast . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

28

5.6.5

Power quality and radio interference . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

28

5.6.6

Operating temperature . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

29

5.6.7

Lamp shape . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

29

5.6.8

Flicker problems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

29

5.6.9

Dimming . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

30

5.6.10 Disposal and recycling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

30

5.7

Lamp sizes and designations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

30

5.8

Other fluorescent lamps . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

30

5.9

Science demonstrations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

31

5.10 See also . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

31

5.11 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

31

5.12 Further reading . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

33

5.13 External links . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

33

5.14 Text and image sources, contributors, and licenses . . . . . . . . . . . . . . . . . . . . . . . . . .

34

5.2

5.3

5.6

CONTENTS

iii

5.14.1 Text . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

34

5.14.2 Images . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

35

5.14.3 Content license . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

37

Chapter 1

Electric arc The phenomenon is believed to be first described by Sir Humphry Davy, in an 1801 paper published in William Nicholson’s Journal of Natural Philosophy, Chemistry and the Arts.[1] However, that was not an electric arc as this phenomenon is considered by the modern science: “This is evidently the description, not of an arc, but of a spark. For the essence of an arc is that it should be continuous, and that the poles should not be in contact after it has once started. The spark produced by Sir Humphry Davy was plainly not continuous; and although the carbons remained red hot for some time after contact, there can have been no arc joining them, or so close an observer would have mentioned it”.[2] In the same year Davy publicly demonstrated the effect, before the Royal Society, by transmitting an electric current through two touching carbon rods and then pulling them a short distance apart. The demonstration produced a “feeble” arc, not readily distinguished from a sustained spark, between charcoal points. The Society subscribed for a more powerful battery of 1000 plates and in 1808 he demonstrated the large-scale arc.[3] He is credited with naming the arc.[4] He called it an arc because it assumes the shape of an upward bow when the distance between the electrodes is not small.[5] This is due to the buoyant force on the hot gas. Independently the phenomenon was discovered in 1802 and described in 1803[6] as a “special fluid with electrical properties”, by Vasily V. Petrov, a Russian scientist experimenting with a copper-zinc battery consisting of 4200 discs.[7]

An electric arc between two nails

An electric arc, or arc discharge, is an electrical breakdown of a gas that produces an ongoing plasma discharge, resulting from a current through normally nonconductive media such as air. An arc discharge is characterized by a lower voltage than a glow discharge, and relies on thermionic emission of electrons from the electrodes supporting the arc. An archaic term is voltaic arc, as used in the phrase “voltaic arc lamp”.

1.1 History

1.2 Overview An electric arc is the form of electric discharge with the highest current density. The maximum current through an arc is limited only by the external circuit, not by the arc itself. The voltage across an arc decreases as the current increases, giving it a dynamic negative resistance characteristic. Where a sustained arc is required, this characteristic requires some external circuit element to stabilize current, which would otherwise increase bounded only by the supply limit. An arc between two electrodes can be initiated by ionization and glow discharge, as the current through the elec-

Lightning is a natural electric arc.

1

2

CHAPTER 1. ELECTRIC ARC gradient and may be absent in very short arcs.[8] A low-frequency (less than 100 Hz) alternating current arc resembles a direct current arc; on each cycle, the arc is initiated by breakdown, and the electrodes interchange roles as anode and cathode as current reverses. As the frequency of the current increases, there is not enough time for all ionization to disperse on each half cycle and the breakdown is no longer needed to sustain the arc; the voltage vs. current characteristic becomes more nearly ohmic.[8]

Electricity arcs between the power rail and electrical pickup “shoe” on a London Underground train

trodes is increased. The breakdown voltage of the electrode gap is a function of the pressure and type of gas surrounding the electrodes. When an arc starts, its terminal voltage is much less than a glow discharge, and current is higher. An arc in gases near atmospheric pressure is characterized by visible light emission, high current density, and high temperature. An arc is distinguished from a glow discharge partly by the approximately equal effective temperatures of both electrons and positive ions; in a glow discharge, ions have much less thermal energy than the electrons. A drawn arc can be initiated by two electrodes initially in contact and drawn apart; this can initiate an arc without the high-voltage glow discharge. This is the way a welder starts to weld a joint, momentarily touching the welding electrode against the workpiece then withdrawing it till a stable arc is formed. Another example is separation of electrical contacts in switches, relays and circuit breakers; in high-energy circuits arc suppression may be required to prevent damage to contacts.[8] Electrical resistance along the continuous electric arc creates heat, which ionizes more gas molecules (where degree of ionization is determined by temperature), and as per this sequence: solid-liquid-gas-plasma; the gas is gradually turned into a thermal plasma. A thermal plasma is in thermal equilibrium; the temperature is relatively homogeneous throughout the atoms, molecules, ions and electrons. The energy given to electrons is dispersed rapidly to the heavier particles by elastic collisions, due to their great mobility and large numbers.

Electric arc between strands of wire.

The various shapes of electric arcs are emergent properties of non-linear patterns of current and electric field. The arc occurs in the gas-filled space between two conductive electrodes (often made of tungsten or carbon) and it results in a very high temperature, capable of melting or vaporizing most materials. An electric arc is a continuous discharge, while the similar electric spark discharge is momentary. An electric arc may occur either in direct current circuits or in alternating current circuits. In the latter case, the arc may re-strike on each half cycle of the current. An electric arc differs from a glow discharge in that the current density is quite high, and the voltage drop within the arc is low; at the cathode, the current density can be as high as one megaampere per square centimeter.[8]

An electric arc has a non-linear relationship between current and voltage. Once the arc is established (either by progression from a glow discharge [9] or by momentarily touching the electrodes then separating them), increased current results in a lower voltage between the arc terminals. This negative resistance effect requires that some positive form of impedance—an electrical ballast—be placed in the circuit to maintain a stable arc. This property is the reason uncontrolled electrical arcs in apparatus Current in the arc is sustained by thermionic emission and become so destructive, since once initiated, an arc will field emission of electrons at the cathode. The current draw more and more current from a fixed-voltage supply may be concentrated in a very small hot spot on the cathuntil the apparatus is destroyed. ode; current densities on the order of one million amperes per square centimetre can be found. Unlike a glow discharge, an arc has little discernible structure, since the positive column is quite bright and extends nearly to the 1.3 Uses electrodes on both ends. The cathode fall and anode fall of a few volts occurs within a fraction of a millimetre of Industrially, electric arcs are used for welding, plasma each electrode. The positive column has a lower potential cutting, for electrical discharge machining, as an arc

1.4. UNDESIRED ARCING

3

Arc damage to a CEE 7/7 plug. The discharge path was formed by a conductive liquid seeping into the plug-socket assembly.

An electric arc can melt calcium oxide

lamp in movie projectors and followspots in stage lighting. Electric arc furnaces are used to produce steel and other substances. Calcium carbide is made in this way as it requires a large amount of energy to promote an endothermic reaction (at temperatures of 2500 °C).

susceptible to arcing are normally designed to contain and extinguish an arc, and snubber circuits can supply a path for transient currents, preventing arcing. If a circuit has enough current and voltage to sustain an arc formed outside of a switching device, the arc can cause damage to equipment such as melting of conductors, destruction of insulation, and fire. An arc flash describes an explosive electrical event that presents a hazard to people and equipment.

Spark plugs are used in petrol internal combustion en- Undesired arcing in electrical contacts of contactors, regines of vehicles to initiate the combustion of the fuel in lays and switches can be reduced by devices such as cona timed fashion. tact arc suppressors[10] and RC Snubbers or through techSpark gaps are also used in electric stove lighters (both niques including: external and built-in). Carbon arc lights were the first electric lights. They were used for street lights in the 19th century and for specialized applications such as searchlights until World War 2. Today, low-pressure electric arcs are used in many applications. For example, fluorescent tubes, mercury, sodium, and metal halide lamps are used for lighting; xenon arc lamps are used for movie projectors. Formation of an intense electric arc, similar to a smallscale arc flash, is the foundation of exploding-bridgewire detonators. Electric arcs have been studied for electric propulsion of spacecraft.

1.4 Undesired arcing

• immersion in transformer oil, dielectric gas or vacuum • arc chutes • magnetic blowouts • pneumatic blowouts • sacrificial (“arcing”) contacts • damping materials to absorb arc energy,either thermally or through chemical decomposition Arcing can also occur when a low resistance channel (foreign object, conductive dust, moisture...) forms between places with different potential. The conductive channel then can facilitate formation of an electric arc. The ionized air has high electrical conductivity approaching that of metals, and can conduct extremely high currents, causing a short circuit and tripping protective devices (fuses, circuit breakers). Similar situation may occur when a lightbulb burns out and the fragments of the filament pull an electric arc between the leads inside the bulb, leading to overcurrent that trips the breakers.

Undesired or unintended electric arcing can have detrimental effects on electric power transmission, distribution systems and electronic equipment. Devices which may cause arcing include switches, circuit breakers, relay contacts, fuses and poor cable terminations. When an inductive circuit is switched off the current cannot instantaneously jump to zero; a transient arc will be Electric arc over the surface of plastics causes their degraformed across the separating contacts. Switching devices dation. A conductive carbon-rich track tends to form

4

CHAPTER 1. ELECTRIC ARC

in the arc path, negatively influencing their insulation properties. The arc susceptibility is tested according to ASTM D495, by point electrodes and continuous and intermittent arcs; it is measured in seconds to form a track that is conductive under high-voltage low-current conditions. Some materials are less susceptible to degradation than others; e.g. polytetrafluoroethylene has arc resistance of about 200 seconds. From thermosetting plastics, alkyds and melamine resins are better than phenolic resins. Polyethylenes have arc resistance of about 150 seconds, polystyrenes and polyvinyl chlorides have relatively low resistance of about 70 seconds. Plastics can be formulated to emit gases with arc-extinguishing properties; these are known as arc-extinguishing plastics. Arcing over some types of printed circuit boards, possibly due to cracks of the traces or the failure of a solder, renders the affected insulating layer conductive as the dielectric is combusted due to the high temperatures involved. This conductivity prolongs the arcing due to cascading failure of the surface.

1.5 Arc suppression Main article: Arc suppression

1.7 References [1] The Electric Arc, By Hertha Ayrton, page 94 [2] The Electric Arc, By Hertha Ayrton, page 20 [3] Luckiesh, Matthew (1920). Artificial light, its influence upon civilization. New York: Century. p. 112. OCLC 1446711. [4] “Arc”. The Columbia Encyclopedia (3rd ed.). New York: Columbia University Press. 1963. LCCN 63020205. [5] Davy, Humphry (1812). Elements of Chemical Philosophy. p. 85. ISBN 0-217-88947-6. This is the likely origin of the term arc. [6] Tracking down the origin of arc plasma Science-II. Early continuous discharges, by André ANDERS [7] Kartsev, V. P. (1983). Shea, William R, ed. Nature Mathematized. Boston, MA: Kluwer Academic. p. 279. ISBN 90-277-1402-9. [8] Howatson, A.M. (1965). An Introduction to Gas Discharges. Oxford: Pergamon Press. pp. 47–101. ISBN 0-08-020575-5. [9] Mehta, V.K. (2005). Principles of Electronics: for Diploma, AMIE, Degree & Other Engineering Examinations (9th ed., multicolour illustrative ed.). New Delhi: S. Chand. pp. 101–107. ISBN 81-219-2450-2.

Arc suppression is a method of attempting to reduce or eliminate the electrical arc. There are several possible [10] “Arc Suppression”. Retrieved December 6, 2013. areas of use of arc suppression methods, among them metal film deposition and sputtering, arc flash protection, [11] “Lab Note #106 Environmental Impact of Arc Suppression". Arc Suppression Technologies. April 2011. Reelectrostatic processes where electrical arcs are not detrieved October 10, 2011. sired (such as powder painting, air purification, PVDF film poling) and contact current arc suppression. In industrial, military and consumer electronic design, the latter method generally applies to devices such as electrome- 1.8 External links chanical power switches, relays and contactors. In this • “High Voltage Arcs and Sparks” Videos of 230 kV context, arc suppression refers to the concept of contact 3-phase “Jacobs Ladder” and unintentional 500 kV protection. power arc Part of the energy of an electrical arc forms new chemical compounds from the air surrounding the arc; these • High Voltage Arc Gap Calculator to calculate the include oxides of nitrogen, and ozone, which can be delength of an arc knowing the voltage or vice versa tected by its distinctive sharp smell. These chemicals can • Ívkisülés Electric arc between two carbon rods. be produced by high-power contacts in relays and moVideo on the portal FizKapu (Hungarian) tor commutators, and are corrosive to nearby metal surfaces. Arcing also erodes the surfaces of the contacts, • Unusual arcing photos wearing them down and creating high contact resistance when closed.[11]

1.6 See also • Arc transmitter • Marx generator • Spark gap • Vacuum arc

Chapter 2

Vacuum arc A vacuum arc can arise when the surfaces of metal electrodes in contact with a good vacuum begin to emit electrons either through heating (thermionic emission) or via an electric field that is sufficient to cause field electron emission. Once initiated, a vacuum arc can persist since the freed particles gain kinetic energy from the electric field, heating the metal surfaces through high speed particle collisions. This process can create an incandescent cathode spot which frees more particles, thereby sustaining the arc. At sufficiently high currents an incandescent anode spot may also be formed.

cal and Spectral Characteristics of a Heated Cathode Discharge in metal Vapors”. Contrib. Plasma Phys. 26 (3): 171–177.

2.2 See also • Electric arc • Gas discharge • Glow discharge

Electrical discharge in vacuum is important for certain types of vacuum tubes and for high voltage vacuum switches.

• Cathodic arc deposition • List of plasma (physics) articles

The thermionic vacuum arc (TVA) is a new type of plasma source, which generates a pure metal and ceramic vapour plasma containing ions with a directed energy. TVA discharges can be ignited in high vacuum conditions between a heated cathode (electron gun) and an anode (tungsten crucible) containing the material. The accelerated electron beam, incident on the anode, heats the crucible, together with its contents, to a high temperature. After establishing a steady-state density of the evaporating anode material atoms, and when the voltage applied is high enough, a bright discharge is ignited between the electrodes.

2.1 References • Messyats, Gennady A.; Proskurovsky, D. I. (1989). Pulsed Electrical Discharge in Vacuum (Springer Series on Atoms and Plasmas, 5) (1st ed.). SpringerVerlag. ISBN 0-387-50725-6. • Greenwood, Allan (1994). Vacuum Switchgear (I E E Power Engineering Series) (1st ed.). Pergamon Press. ISBN 0-85296-855-8. • Musa, Geavit; Betiu, Nicolae; Mustata, Ion; Baltog, Alexandra; Popescu, Alexandra (1983). “Low Voltage Arc Welding in Vacuum”. Rev. Roum. Phys 28 (10): 907–908. • Musa, Geavit; Baltog, Alexandra; Popescu, Alexandra; Betiu, Nicolae; Mustata, Ion (1986). “Electri5

Chapter 3

Cathodic arc deposition Cathodic arc deposition or Arc-PVD is a physical vapor deposition technique in which an electric arc is used to vaporize material from a cathode target. The vaporized material then condenses on a substrate, forming a thin film. The technique can be used to deposit metallic, ceramic, and composite films.

will be deposited. One downside of the arc evaporation process is that if the cathode spot stays at an evaporative point for too long it can eject a large amount of macro-particles or droplets. These droplets are detrimental to the performance of the coating as they are poorly adhered and can extend through the coating. Worse still if the cathode target material has a low melting point such as aluminium the cathode spot can evaporate through the target resulting in either the target backing plate material being evaporated or cooling water entering the chamber. Therefore magnetic fields as mentioned previously are used to control the motion of the arc. If cylindrical cathodes are used the cathodes can also be rotated during deposition. By not allowing the cathode spot to remain in one position too long aluminium targets can be used and the number of droplets is reduced. Some companies also use filtered arcs that use magnetic fields to separate the droplets from the coating flux.

3.1 History Industrial use of modern cathodic arc deposition technology originated in Soviet Union around 1960–1970. By the late 70’s Soviet government released the use of this technology to the West. Among many designs in USSR at that time the design by L. P. Sablev, et al., was allowed to be used outside the USSR.

3.2 Process The arc evaporation process begins with the striking of a high current, low voltage arc on the surface of a cathode (known as the target) that gives rise to a small (usually a few micrometres wide), highly energetic emitting area known as a cathode spot. The localised temperature at the cathode spot is extremely high (around 15000 °C), which results in a high velocity (10 km/s) jet of vapourised cathode material, leaving a crater behind on the cathode surface. The cathode spot is only active for a short period of time, then it self-extinguishes and re-ignites in a new area close to the previous crater. This behaviour causes the apparent motion of the arc.

3.3 Equipment design

As the arc is basically a current carrying conductor it can be influenced by the application of an electromagnetic field, which in practice is used to rapidly move the arc over the entire surface of the target, so that the total surface is eroded over time. The arc has an extremely high power density resulting in a high level of ionization (30-100%), multiple charged ions, neutral particles, clusters and macro-particles (droplets). If a reactive gas is introduced during the evaporation process, dissociation, ionization and excitation can occur during interaction with the ion flux and a compound film

Sablev type Cathodic arc source with magnet to steer the movement of arc spot

Sablev type Cathodic arc source, which is the most widely used in the West, consists of a short cylindrical shape electrical conductive target at cathode with one open end. 6

3.5. SEE ALSO

7

This target has an electrically-floating metal ring surrounded working as an arc confinement ring. The anode for the system can be either the vacuum chamber wall or a discrete anode. Arc spots are generated by mechanical trigger (or igniter) striking on open end of the target making a temporarily short circuit between the cathode and anode. After the arc spots being generated they can be steered by magnetic field or move randomly in absence of magnetic field. Titanium Nitride (TiN) coated punches using Cathodic arc deposition technique

Aluminium Titanium Nitride (AlTiN) coated endmills using Cathodic arc deposition technique Aksenov Quarter-torus duct macroparticle filter using plasma optical principles which was developed by A. I. Morozov

The plasma beam from Cathodic Arc source contains some larger clusters of atoms or molecules (so called macro-particles), which prevent it from being useful for some applications without some kind of filtering. There are many designs for macro-particle filters and the most studied design is based on the work by I. I. Aksenov et al. in 70’s. It consists of a quarter-torus duct bent at 90 degrees from the arc source and the plasma is guided out of the duct by principle of plasma optics. There are also other interesting designs such as a design which incorporates a straight duct filter built-in with truncated cone shape cathode as reported by D. A. Karpov in the 90’s. This design became quite popular among both the thin hard-film coaters and researchers in Russia and former USSR countries until now. Cathodic arc source can be made into the long tubular shape (extended-arc) or long rectangular shape but both designs are less popular.

3.4 Applications

Aluminium Chromium Titanium Nitride (AlCrTiN) coated Hob using Cathodic arc deposition technique

cause the ions are blasted from the surface ballistically, it is common for not only single atoms, but larger clusters of atoms to be ejected. Thus, this kind of system requires a filter to remove atom clusters from the beam before deposition. The DLC film from filtered-arc contains extremely high percentage of sp3 diamond which is known as tetrahedral amorphous carbon, or ta-C.

Filtered Cathodic arc can be used as metal ion/plasma Cathodic arc deposition is actively used to synthesize ex- source for Ion implantation and Plasma Immersion Ion tremely hard film to protect the surface of cutting tools Implantation and Deposition (PIII&D). and extend their life significantly. A wide variety of thin hard-film, Superhard coatings and nanocomposite coatings can be synthesized by this technology including TiN, 3.5 See also TiAlN, CrN, ZrN, AlCrTiN and TiAlSiN. This is also used quite extensively particularly for carbon ion deposition to create diamond-like carbon films. Be-

• Ion beam deposition

8

CHAPTER 3. CATHODIC ARC DEPOSITION • Physical vapor deposition

3.6 References • SVC “51st Annual Technical Conference Proceedings” (2008) Society of Vacuum Coaters, ISSN 0737-5921 (previous proceedings available on CD from SVC Publications) • A. Anders, “Cathodic Arcs: From Fractal Spots to Energetic Condensation” (2008) Springer, New York. • R. L. Boxman, D. M. Sanders, and P. J. Martin (editors) “Handbook of Vacuum Arc Science and Technology"(1995) Noyes Publications, Park Ridge, N.J. • Brown, I.G., Annual Rev. Mat. Sci. 28, 243 (1998). • Sablev et al., US Patent #3,783,231, 01 Jan. 1974 • Sablev et al., US Patent #3,793,179, 19 Feb. 1974 • D. A. Karpov, “Cathodic arc sources and macroparticle filtering”, Surface and Coatings technology 96 (1997) 22-23 • S. Surinphong, “Basic Knowledge about PVD Systems and Coatings for Tools Coating” (1998), in Thai language • A. I. Morozov, Reports of the Academy of Sciences of the USSR, 163 (1965) 1363, in Russian language • I. I. Aksenov, V. A. Belous, V. G. Padalka, V. M. Khoroshikh, “Transport of plasma streams in a curvilinear plasma-optics system”, Soviet Journal of Plasma Physics, 4 (1978) 425 • http://www.researchgate.net/publication/ 273004395_Arc_source_designs • http://www.researchgate.net/profile/Dmitri_ Karpov/publications/2 • https://www.researchgate.net/publication/ 234202890_Transport_of_plasma_streams_ in_a_curvilinear_plasma-optics_system

Chapter 4

Glow discharge ing electricity, causing it to glow with a colored light. The color depends on the gas used. Glow discharge is widely used as a source of light in devices such as neon lights, fluorescent lamps, and plasma-screen televisions. Analyzing the light produced by spectroscopy can reveal much about the atomic interactions in the gas, so glow discharge is used in plasma physics and analytical chemistry. It is also used in the surface treatment technique called sputtering.

4.1 Basic operating mechanism

A glow discharge tube featuring its most important characteristics: (a) An anode at one end and cathode at the other end (b) Aston Dark Space(c) Cathode glow (d) Cathode dark space (also called Crookes dark space, or Hittorf dark space) (e) Negative glow (f) Faraday space (g) Positive column (h) Anode glow (i) Anode dark space.

This system was first made by William Crookes. The simplest type of glow discharge is a direct-current glow discharge. In its simplest form, it consists of two electrodes in a cell held at low pressure (0.1–10 torr; about 1/10000th to 1/100th of atmospheric pressure). The cell is typically filled with neon, but other gases can also be used. An electric potential of several hundred volts is applied between the two electrodes. A small fraction of the population of atoms within the cell is initially ionized through random processes (thermal collisions between atoms or with gamma rays, for example). The ions (which are positively charged) are driven towards the cathode by the electric potential, and the electrons are driven towards the anode by the same potential. The initial population of ions and electrons collides with other atoms, ionizing them. As long as the potential is maintained, a population

Neon lamp, 1/2 inch, showing glow discharge surrounding cathode.

A glow discharge is a plasma formed by the passage of electric current through a low-pressure gas. It is created by applying a voltage between two metal electrodes in a glass tube containing gas. When the voltage exceeds a certain value called the striking voltage, the gas in the tube ionizes, becoming a plasma, and begins conduct9

10

CHAPTER 4. GLOW DISCHARGE

of ions and electrons remains.

amount of that element in the sample.

K 10 0

Current (A)

Arc

J Abnormal Glow H G Normal F Glow

10−5

I Glow Discharge

E

F'

"breakdown"

D

E'

10−10

C B

A 10−15

B'

A' 0

Dark Discharge

200

400

600

800

1000

Voltage (V) Current-voltage curve (characteristic curve) of a discharge in neon gas at a pressure of 1 torr, showing the different regions. The vertical (current) scale is logarithmic.

Some of the ions’ kinetic energy is transferred to the cathode. This happens partially through the ions striking the cathode directly. The primary mechanism, however, is less direct. Ions strike the more numerous neutral gas atoms, transferring a portion of their energy to them. These neutral atoms then strike the cathode. Whichever species (ions or atoms) strike the cathode, collisions within the cathode redistribute this energy until a portion of the cathode is ejected, typically in the form of free atoms. This process is known as sputtering. Once free of the cathode, atoms move into the bulk of the glow discharge through drift and due to the energy they gained from sputtering. The atoms can then be excited by collisions with ions, electrons, or other atoms that have been previously excited by collisions. Once excited, atoms will lose their energy fairly quickly. Of the various ways that this energy can be lost, the most important is radiatively, meaning that a photon is released to carry the energy away. In optical atomic spectroscopy, the wavelength of this photon can be used to determine the identity of the atom (that is, which chemical element it is) and the number of photons is directly proportional to the concentration of that element in the sample. Some collisions (those of high enough energy) will cause ionization. In atomic mass spectrometry, these ions are detected. Their mass identifies the type of atoms and their quantity reveals the

The figure above shows the main regions that may be present in a glow discharge. Regions described as “glows” emit significant light; regions labeled as “dark spaces” do not. As the discharge becomes more extended (i.e., stretched horizontally in the geometry of the figure), the positive column may become striated. That is, alternating dark and bright regions may form. Compressing the discharge horizontally will result in fewer regions. The positive column will be compressed while the negative glow will remain the same size, and, with small enough gaps, the positive column will disappear altogether. In an analytical glow discharge, the discharge is primarily a negative glow with dark region above and below it. Below the ionization voltage or breakdown voltage there is no glow, but as the voltage increases to the ionization point the Townsend discharge happens just as glow discharge becomes visible; this is the start of the normal glow range. As the voltage is increased above the normal glow range, abnormal glow begins. If the voltage is increased to the point the cathode glow covers the entire cathode arc discharge begins.[1]

4.2 Use in analytical chemistry Glow discharges can be used to analyze the elemental, and sometimes molecular, composition of solids, liquids, and gases, but elemental analysis of solids is the most common. In this arrangement, the sample is used as the cathode. As mentioned earlier, gas ions and atoms striking the sample surface knock atoms off of it, a process known as sputtering. The sputtered atoms, now in the gas phase, can be detected by atomic absorption, but this is a comparatively rare strategy. Instead, atomic emission and mass spectrometry are usually used. Collisions between the gas-phase sample atoms and the plasma gas pass energy to the sample atoms. This energy can excite the atoms, after which they can lose their energy through atomic emission. By observing the wavelength of the emitted light, the atom’s identity can be determined. By observing the intensity of the emission, the concentration of atoms of that type can be determined. Energy gained through collisions can also ionize the sample atoms. The ions can then be detected by mass spectrometry. In this case, it is the mass of the ions that identify the element and the number of ions that reflect the concentration. This method is referred to as glow discharge mass spectrometry (GDMS) and it has detection limits down to the sub-ppb range for most elements that are nearly matrix-independent. Both bulk and depth analysis of solids may be performed with glow discharge. Bulk analysis assumes that the sample is fairly homogeneous and averages the emission or mass spectrometric signal over time. Depth analysis relies on tracking the signal in time, therefore, is the same

4.5. APPLICATION TO ANALOG COMPUTING as tracking the elemental composition in depth. Depth analysis requires greater control over operational parameters. For example, conditions (current, potential, pressure) need to be adjusted so that the crater produced by sputtering is flat bottom (that is, so that the depth analyzed over the crater area is uniform). In bulk measurement, a rough or rounded crater bottom would not adversely impact analysis. Under the best conditions, depth resolution in the single nanometer range has been achieved (in fact, within-molecule resolution has been demonstrated). The chemistry of ions and neutrals in vacuum is called gas phase ion chemistry and is part of the analytical study that includes glow discharge.

4.3 Powering modes In analytical chemistry, glow discharges are most often operated in direct-current mode. For this mode, the cathode (which is the sample in solids analysis) must be conductive. The potential, pressure, and current are interrelated. Only two can be directly controlled at once, while the third must be allowed to vary. The pressure is most typically held constant, but other schemes may be used. The pressure and current may be held constant, while potential is allowed to vary. The pressure and voltage may be held constant while the current is allowed to vary. The power (product of voltage and current) may be held constant while the pressure is allowed to vary. Glow discharges may also be operated in radio-frequency. The use of this frequency will establish a negative DCbias voltage on the sample surface. The DC-bias is the result of an alternating current waveform that is centered about negative potential; as such it more or less represent the average potential residing on the sample surface. Radio-frequency has ability to appear to flow through insulators (non-conductive materials). Both radio-frequency and direct-current glow discharges can be operated in pulsed mode, where the potential is turned on and off. This allows higher instantaneous powers to be applied without excessively heating the cathode. These higher instantaneous powers produce higher instantaneous signals, aiding detection. Combining timeresolved detection with pulsed powering results in additional benefits. In atomic emission, analyte atoms emit during different portions of the pulse than background atoms, allowing the two to be discriminated. Analogously, in mass spectrometry, sample and background ions are created at different times.

11

4.5 Application to analog computing An interesting application for using glow discharge was described in a 2002 scientific paper by Ryes, Ghanem et al.[2] According to a Nature news article describing the work,[3] researchers at Imperial College London demonstrated how they built a mini-map that glows along the shortest route between two points. The Nature news article describes the system as follows: To make the one-inch London chip, the team etched a plan of the city centre on a glass slide. Fitting a flat lid over the top turned the streets into hollow, connected tubes. They filled these with helium gas, and inserted electrodes at key tourist hubs. When a voltage is applied between two points, electricity naturally runs through the streets along the shortest route from A to B - and the gas glows like a tiny neon strip light. The approach itself provides a novel visible analog computing approach for solving a wide class of maze searching problems based on the properties of lighting up of a glow discharge in a microfluidic chip.

4.6 See also • Electric arc discharge • Vacuum arc • X-ray tube • Fluorescent lamp, neon lamp, and plasma lamp • List of plasma (physics) articles

4.7 References [1] Principles of Electronics By V.K. Mehta ISBN 81-2192450-2

4.4 Types

[2] Reyes, D. R.; Ghanem, M. M.; Whitesides, G. M.; Manz, A. (2002). “Glow discharge in microfluidic chips for visible analog computing”. Lab on a Chip (ACS) 2 (2): 113– 6. doi:10.1039/B200589A. PMID 15100843.

There are various types of glow discharge examples include: high pressure glow discharge, hollow cathode discharge, spray discharge.

[3] Mini-map gives tourists neon route http://www.nature.com/news/2002/020527/full/ news020520-12.html

signs:

12

4.8 Further reading • S. Flügge, ed. (1956). Handbuch der Physik/Encyclopedia of Physics band/volume XXI - Electron-emission • Gas discharges I. SpringerVerlag. First chapter of the article Secondary effects by P.F. Little. • R. Kenneth Marcus (Ed.) (1993). Glow Discharge Spectroscopies. Kluwer Academic Publishers (Modern Analytical Chemistry). ISBN 0-306-44396-1.

CHAPTER 4. GLOW DISCHARGE

Chapter 5

Fluorescent lamp

Fluorescent lamps Typical F71T12 100 W bi-pin lamp used in tanning beds. The (Hg) symbol indicates that this lamp contains mercury. In the US, this symbol is now required on all fluorescent lamps that contain mercury.[1]

Top, two compact fluorescent lamps. Bottom, two fluorescent tube lamps. A matchstick, left, is shown for scale.

One style of lamp holder for T12 and T8 bi pin fluorescent lamps Compact fluorescent lamp with electronic ballast

13

14

CHAPTER 5. FLUORESCENT LAMP scientist Sir George Stokes from the University of Cambridge, who named the phenomenon “fluorescence” after fluorite, a mineral many of whose samples glow strongly due to impurities. The explanation relied on the nature of electricity and light phenomena as developed by the British scientists Michael Faraday in the 1840s and James Clerk Maxwell in the 1860s.[4]

Inside the lamp end of a preheat bi-pin lamp. In this lamp the filament is surrounded by an oblong metal cathode shield, which helps reduce lamp end darkening.[2]

A fluorescent lamp or a fluorescent tube is a low pressure mercury-vapor gas-discharge lamp that uses fluorescence to produce visible light. An electric current in the gas excites mercury vapor which produces shortwave ultraviolet light that then causes a phosphor coating on the inside of the bulb to glow. A fluorescent lamp converts electrical energy into useful light much more efficiently than incandescent lamps. The luminous efficacy of a fluorescent light bulb can exceed 100 lumens per watt, several times the efficacy of an incandescent bulb with comparable light output. Fluorescent lamp fixtures are more costly than incandescent lamps because they require a ballast to regulate the current through the lamp, but the lower energy cost typically offsets the higher initial cost. Compact fluorescent lamps are now available in the same popular sizes as incandescents and are used as an energy-saving alternative in homes.

Little more was done with this phenomenon until 1856 when a German glassblower named Heinrich Geissler created a mercury vacuum pump that evacuated a glass tube to an extent not previously possible. When an electrical current passed through a Geissler tube, a strong green glow on the walls of the tube at the cathode end could be observed. Because it produced some beautiful light effects, the Geissler tube was a popular source of amusement. More important, however, was its contribution to scientific research. One of the first scientists to experiment with a Geissler tube was Julius Plücker who systematically described in 1858 the luminescent effects that occurred in a Geissler tube. He also made the important observation that the glow in the tube shifted position when in proximity to an electromagnetic field. Alexandre Edmond Becquerel observed in 1859 that certain substances gave off light when they were placed in a Geissler tube. He went on to apply thin coatings of luminescent materials to the surfaces of these tubes. Fluorescence occurred, but the tubes were very inefficient and had a short operating life.[5] Inquiries that began with the Geissler tube continued as even better vacuums were produced. The most famous was the evacuated tube used for scientific research by William Crookes. That tube was evacuated by the highly effective mercury vacuum pump created by Hermann Sprengel. Research conducted by Crookes and others ultimately led to the discovery of the electron in 1897 by J. J. Thomson and X-rays in 1895 by Wilhelm Roentgen. But the Crookes tube, as it came to be known, produced little light because the vacuum in it was too good and thus lacked the trace amounts of gas that are needed for electrically stimulated luminescence.

Because they contain mercury, many fluorescent lamps are classified as hazardous waste. The United States Environmental Protection Agency recommends that fluores- 5.1.2 Early discharge lamps cent lamps be segregated from general waste for recycling or safe disposal.[3] While Becquerel was interested primarily in conducting scientific research into fluorescence, Thomas Edison briefly pursued fluorescent lighting for its commercial potential. He invented a fluorescent lamp in 1896 that used a 5.1 History coating of calcium tungstate as the fluorescing substance, excited by X-rays, but although it received a patent in 5.1.1 Physical discoveries 1907,[6] it was not put into production. As with a few other attempts to use Geissler tubes for illumination, it Fluorescence of certain rocks and other substances had had a short operating life, and given the success of the been observed for hundreds of years before its nature incandescent light, Edison had little reason to pursue an was understood. By the middle of the 19th century, ex- alternative means of electrical illumination. Nikola Tesla perimenters had observed a radiant glow emanating from made similar experiments in the 1890s, devising highpartially evacuated glass vessels through which an electric frequency powered fluorescent bulbs that gave a bright current passed. One of the first to explain it was the Irish greenish light, but as with Edison’s devices, no commer-

5.1. HISTORY

15

Peter Cooper Hewitt

vantages of Moore’s lamp, but GE purchased the relevant patents in 1912. These patents and the inventive efOne of the first mercury vapor lamps invented by Peter Cooper forts that supported them were to be of considerable value Hewitt, 1903. It was similar to a fluorescent lamp without the when the firm took up fluorescent lighting more than two fluorescent coating on the tube, and produced greenish light. The decades later. round device under the lamp is the ballast.

cial success was achieved. Although Edison lost interest in fluorescent lighting, one of his former employees was able to create a gas-based lamp that achieved a measure of commercial success. In 1895 Daniel McFarlan Moore demonstrated lamps 2 to 3 meters (6.6 to 9.8 ft) in length that used carbon dioxide or nitrogen to emit white or pink light, respectively. As with future fluorescent lamps, they were considerably more complicated than an incandescent bulb.[7] After years of work, Moore was able to extend the operating life of the lamps by inventing an electromagnetically controlled valve that maintained a constant gas pressure within the tube.[8] Although Moore’s lamp was complicated, was expensive to install, and required very high voltages, it was considerably more efficient than incandescent lamps, and it produced a closer approximation to natural daylight than contemporary incandescent lamps. From 1904 onwards Moore’s lighting system was installed in a number of stores and offices.[9] Its success contributed to General Electric’s motivation to improve the incandescent lamp, especially its filament. GE’s efforts came to fruition with the invention of a tungstenbased filament. The extended lifespan and improved efficacy of incandescent bulbs negated one of the key ad-

At about the same time that Moore was developing his lighting system, another American was creating a means of illumination that also can be seen as a precursor to the modern fluorescent lamp. This was the mercury-vapor lamp, invented by Peter Cooper Hewitt and patented in 1901 (US 682692; this patent number is frequently misquoted as US 889,692). Hewitt’s lamp glowed when an electric current was passed through mercury vapor at a low pressure. Unlike Moore’s lamps, Hewitt’s were manufactured in standardized sizes and operated at low voltages. The mercury-vapor lamp was superior to the incandescent lamps of the time in terms of energy efficiency, but the blue-green light it produced limited its applications. It was, however, used for photography and some industrial processes. Mercury vapor lamps continued to be developed at a slow pace, especially in Europe, and by the early 1930s they received limited use for large-scale illumination. Some of them employed fluorescent coatings, but these were used primarily for color correction and not for enhanced light output. Mercury vapor lamps also anticipated the fluorescent lamp in their incorporation of a ballast to maintain a constant current. Cooper-Hewitt had not been the first to use mercury vapor for illumination, as earlier efforts had been mounted by Way, Rapieff, Arons, and Bastian and Salisbury. Of

16

CHAPTER 5. FLUORESCENT LAMP

particular importance was the mercury vapor lamp invented by Küch in Germany. This lamp used quartz in place of glass to allow higher operating temperatures, and hence greater efficiency. Although its light output relative to electrical consumption was better than that of other sources of light, the light it produced was similar to that of the Cooper-Hewitt lamp in that it lacked the red portion of the spectrum, making it unsuitable for ordinary lighting.

5.1.3

Neon lamps

Main article: Neon lighting The next step in gas-based lighting took advantage of the luminescent qualities of neon, an inert gas that had been discovered in 1898 by isolation from the atmosphere. Neon glowed a brilliant red when used in Geissler tubes.[10] By 1910, Georges Claude, a Frenchman who had developed a technology and a successful business for air liquefaction, was obtaining enough neon as a byproduct to support a neon lighting industry.[11][12] While neon lighting was used around 1930 in France for general illumination, it was no more energy-efficient than conventional incandescent lighting. Neon tube lighting, which also includes the use of argon and mercury vapor as alternate gases, came to be used primarily for eye-catching signs and advertisements. Neon lighting was relevant to the development of fluorescent lighting, however, as Claude’s improved electrode (patented in 1915) overcame “sputtering”, a major source of electrode degradation. Sputtering occurred when ionized particles struck an electrode and tore off bits of metal. Although Claude’s invention required electrodes with a lot of surface area, it showed that a major impediment to gas-based lighting could be overcome. The development of the neon light also was significant for the last key element of the fluorescent lamp, its fluorescent coating. In 1926 Jacques Risler received a French patent for the application of fluorescent coatings to neon light tubes.[9] The main use of these lamps, which can be considered the first commercially successful fluorescents, was for advertising, not general illumination. This, however, was not the first use of fluorescent coatings; Edison used calcium tungstate for his unsuccessful lamp. Other efforts had been mounted, but all were plagued by low efficiency and various technical problems. Of particular importance was the invention in 1927 of a low-voltage “metal vapor lamp” by Friedrich Meyer, Hans-Joachim Spanner, and Edmund Germer, who were employees of a German firm in Berlin. A German patent was granted but the lamp never went into commercial production.

5.1.4 Commercialization of fluorescent lamps All the major features of fluorescent lighting were in place at the end of the 1920s. Decades of invention and development had provided the key components of fluorescent lamps: economically manufactured glass tubing, inert gases for filling the tubes, electrical ballasts, longlasting electrodes, mercury vapor as a source of luminescence, effective means of producing a reliable electrical discharge, and fluorescent coatings that could be energized by ultraviolet light. At this point, intensive development was more important than basic research. In 1934, Arthur Compton, a renowned physicist and GE consultant, reported to the GE lamp department on successful experiments with fluorescent lighting at General Electric Co., Ltd. in Great Britain (unrelated to General Electric in the United States). Stimulated by this report, and with all of the key elements available, a team led by George E. Inman built a prototype fluorescent lamp in 1934 at General Electric’s Nela Park (Ohio) engineering laboratory. This was not a trivial exercise; as noted by Arthur A. Bright, “A great deal of experimentation had to be done on lamp sizes and shapes, cathode construction, gas pressures of both argon and mercury vapor, colors of fluorescent powders, methods of attaching them to the inside of the tube, and other details of the lamp and its auxiliaries before the new device was ready for the public.”[9] In addition to having engineers and technicians along with facilities for R&D work on fluorescent lamps, General Electric controlled what it regarded as the key patents covering fluorescent lighting, including the patents originally issued to Hewitt, Moore, and Küch. More important than these was a patent covering an electrode that did not disintegrate at the gas pressures that ultimately were employed in fluorescent lamps. Albert W. Hull of GE’s Schenectady Research Laboratory filed for a patent on this invention in 1927, which was issued in 1931.[13] General Electric used its control of the patents to prevent competition with its incandescent lights and probably delayed the introduction of fluorescent lighting by 20 years. Eventually, war production required 24-hour factories with economical lighting and fluorescent lights became available. While the Hull patent gave GE a basis for claiming legal rights over the fluorescent lamp, a few months after the lamp went into production the firm learned of a U.S. patent application that had been filed in 1927 for the aforementioned “metal vapor lamp” invented in Germany by Meyer, Spanner, and Germer. The patent application indicated that the lamp had been created as a superior means of producing ultraviolet light, but the application also contained a few statements referring to fluorescent illumination. Efforts to obtain a U.S. patent had met with numerous delays, but were it to be granted, the patent might have caused serious difficulties for GE. At first,

5.2. PRINCIPLES OF OPERATION GE sought to block the issuance of a patent by claiming that priority should go to one of their employees, Leroy J. Buttolph, who according to their claim had invented a fluorescent lamp in 1919 and whose patent application was still pending. GE also had filed a patent application in 1936 in Inman’s name to cover the “improvements” wrought by his group. In 1939 GE decided that the claim of Meyer, Spanner, and Germer had some merit, and that in any event a long interference procedure was not in their best interest. They therefore dropped the Buttolph claim and paid $180,000 to acquire the Meyer, et al. application, which at that point was owned by a firm known as Electrons, Inc. The patent was duly awarded in December 1939.[14] This patent, along with the Hull patent, put GE on what seemed to be firm legal ground, although it faced years of legal challenges from Sylvania Electric Products, Inc., which claimed infringement on patents that it held. Even though the patent issue would not be completely resolved for many years, General Electric’s strength in manufacturing and marketing the bulb gave it a pre-eminent position in the emerging fluorescent light market. Sales of “fluorescent lumiline lamps” commenced in 1938 when four different sizes of tubes were put on the market used in fixtures manufactured by three leading corporations, Lightolier, Artcraft Fluorescent Lighting Corporation, and Globe Lighting, two based in New York City. During the following year GE and Westinghouse publicized the new lights through exhibitions at the New York World’s Fair and the Golden Gate International Exposition in San Francisco. Fluorescent lighting systems spread rapidly during World War II as wartime manufacturing intensified lighting demand. By 1951 more light was produced in the United States by fluorescent lamps than by incandescent lamps.[15]

17 wavelengths in the ultraviolet (UV) region of the spectrum, predominantly at wavelengths of 253.7 and 185 nanometers (nm). These are not visible to the human eye, so they must be converted into visible light. This is done by making use of fluorescence. Ultraviolet photons are absorbed by electrons in the atoms of the lamp’s interior fluorescent coating, causing a similar energy jump, then drop, with emission of a further photon. The photon that is emitted from this second interaction has a lower energy than the one that caused it. The chemicals that make up the phosphor are chosen so that these emitted photons are at wavelengths visible to the human eye. The difference in energy between the absorbed ultra-violet photon and the emitted visible light photon goes toward heating up the phosphor coating. When the light is turned on, the electric power heats up the cathode enough for it to emit electrons (thermionic emission). These electrons collide with and ionize noble gas atoms inside the bulb surrounding the filament to form a plasma by the process of impact ionization. As a result of avalanche ionization, the conductivity of the ionized gas rapidly rises, allowing higher currents to flow through the lamp. The fill gas helps determine the operating electrical characteristics of the lamp, but does not give off light itself. The fill gas effectively increases the distance that electrons travel through the tube, which allows an electron a greater chance of interacting with a mercury atom. Argon atoms, excited to a metastable state by impact of an electron, can impart this energy to a neutral mercury atom and ionize it, described as the Penning effect. This has the benefit of lowering the breakdown and operating voltage of the lamp, compared to other possible fill gases such as krypton.[17]

In the first years zinc orthosilicate with varying content of beryllium was used as greenish phosphor. Small additions of magnesium tungstate improved the blue part 5.2.1 Construction of the spectrum yielding acceptable white. After it was discovered that beryllium was toxic, halophosphate based A fluorescent lamp tube is filled with a gas containphosphors took over.[16] ing low pressure mercury vapor and argon, xenon, neon, or krypton. The pressure inside the lamp is around 0.3% of atmospheric pressure.[18] The inner surface of the lamp is coated with a fluorescent (and often 5.2 Principles of operation slightly phosphorescent) coating made of varying blends of metallic and rare-earth phosphor salts. The lamp’s The fundamental means for conversion of electrical en- electrodes are typically made of coiled tungsten and usuergy into radiant energy in a fluorescent lamp relies on ally referred to as cathodes because of their prime funcinelastic scattering of electrons when an incident electron tion of emitting electrons. For this, they are coated with a collides with an atom in the gas. If the (incident) free mixture of barium, strontium and calcium oxides chosen electron has enough kinetic energy, it transfers energy to to have a low thermionic emission temperature. the atom’s outer electron, causing that electron to tem- Fluorescent lamp tubes are typically straight and range porarily jump up to a higher energy level. The collision in length from about 100 millimeters (3.9 in) for miniais 'inelastic' because a loss of kinetic energy occurs. ture lamps, to 2.43 meters (8.0 ft) for high-output lamps. This higher energy state is unstable, and the atom will emit an ultraviolet photon as the atom’s electron reverts to a lower, more stable, energy level. Most of the photons that are released from the mercury atoms have

Some lamps have the tube bent into a circle, used for table lamps or other places where a more compact light source is desired. Larger U-shaped lamps are used to provide the same amount of light in a more compact area, and are

18

CHAPTER 5. FLUORESCENT LAMP

Close-up of the cathodes of a germicidal lamp (an essentially similar design that uses no fluorescent phosphor, allowing the electrodes to be seen.)

used for special architectural purposes. Compact fluorescent lamps have several small-diameter tubes joined in a bundle of two, four, or six, or a small diameter tube coiled into a helix, to provide a high amount of light output in little volume. Light-emitting phosphors are applied as a paint-like coating to the inside of the tube. The organic solvents are allowed to evaporate, then the tube is heated to nearly The unfiltered ultraviolet glow of a germicidal lamp is produced by a low pressure mercury vapor discharge (identical to that in a the melting point of glass to drive off remaining organic fluorescent lamp) in an uncoated fused quartz envelope. compounds and fuse the coating to the lamp tube. Careful control of the grain size of the suspended phosphors is necessary; large grains, 35 micrometers or larger, lead to weak grainy coatings, whereas too many small particles 1 or 2 micrometers or smaller leads to poor light maintenance and efficiency. Most phosphors perform best with a particle size around 10 micrometers. The coating must be thick enough to capture all the ultraviolet light produced by the mercury arc, but not so thick that the phosphor coating absorbs too much visible light. The first phosphors were synthetic versions of naturally occurring fluorescent minerals, with small amounts of metals added as activators. Later other compounds were discovered, allowing differing colors of lamps to be made.[19]

5.2.2

Electrical aspects of operation

Different ballasts for fluorescent and discharge lamps

Fluorescent lamps are negative differential resistance de- for even more current to flow. Connected directly to a vices, so as more current flows through them, the elec- constant-voltage power supply, a fluorescent lamp would trical resistance of the fluorescent lamp drops, allowing rapidly self-destruct due to the uncontrolled current flow.

5.2. PRINCIPLES OF OPERATION

19

To prevent this, fluorescent lamps must use an auxiliary 5.2.3 device, a ballast, to regulate the current flow through the lamp.

Effect of temperature

The terminal voltage across an operating lamp varies depending on the arc current, tube diameter, temperature, and fill gas. A fixed part of the voltage drop is due to the electrodes. A general lighting service 48-inch (1,219 mm) T12[20] lamp operates at 430 mA, with 100 volts drop. High output lamps operate at 800 mA, and some types operate up to 1.5 A. The power level varies from 33 to 82 watts per meter of tube length (10 to 25 W/ft) for T12 lamps.[21] The simplest ballast for alternating current (AC) use is an inductor placed in series, consisting of a winding on a laminated magnetic core. The inductance of this winding limits the flow of AC current. This type is still used, for example, in 120 volt operated desk lamps using relatively short lamps. Ballasts are rated for the size of lamp and power frequency. Where the AC voltage is insufficient to start long fluorescent lamps, the ballast is often a step-up autotransformer with substantial leakage inductance (so as to limit the current flow). Either form of inductive ballast may also include a capacitor for power factor correction.

Thermal image of a helical fluorescent lamp.

230 V ballast for 18–20 W

By using an amalgam with some other metal, the vapor pressure is reduced and the optimum temperature range extended upward; however, the bulb wall “cold spot” temperature must still be controlled to prevent migration of the mercury out of the amalgam and condensing on the cold spot. Fluorescent lamps intended for higher output will have structural features such as a deformed tube or internal heat-sinks to control cold spot temperature and mercury distribution. Heavily loaded small lamps, such as compact fluorescent lamps, also include heat-sink areas in the tube to maintain mercury vapor pressure at the optimum value.[22]

Many different circuits have been used to operate fluorescent lamps. The choice of circuit is based on AC voltage, tube length, initial cost, long term cost, instant versus non-instant starting, temperature ranges and parts availability, etc. Fluorescent lamps can run directly from a direct current (DC) supply of sufficient voltage to strike an arc. The ballast must be resistive, and would consume about as much power as the lamp. When operated from DC, the starting switch is often arranged to reverse the polarity of the supply to the lamp each time it is started; otherwise, the mercury accumulates at one end of the tube. Fluorescent lamps are (almost) never operated directly from DC for those reasons. Instead, an inverter converts the DC into AC and provides the current-limiting function as described below for electronic ballasts.

The light output and performance of fluorescent lamps is critically affected by the temperature of the bulb wall and its effect on the partial pressure of mercury vapor within the lamp.[19] Each lamp contains a small amount of mercury, which must vaporize to support the lamp current and generate light. At low temperatures the mercury is in the form of dispersed liquid droplets. As the lamp warms, more of the mercury is in vapor form. At higher temperatures, self-absorption in the vapor reduces the yield of UV and visible light. Since mercury condenses at the coolest spot in the lamp, careful design is required to maintain that spot at the optimum temperature, around 40 °C (104 °F).

5.2.4 Losses Only a fraction of the electrical energy input into a lamp is converted to useful light. The ballast dissipates some heat; electronic ballasts may be around 90% efficient. A fixed voltage drop occurs at the electrodes, which also produces heat. Some of the energy in the mercury vapor column is also dissipated, but about 85% is turned into visible and ultraviolet light. The UV light is absorbed by the lamp’s fluorescent coat-

20

CHAPTER 5. FLUORESCENT LAMP tered material so it is not lost from the electrode. 40 watts power in Ballast 90%

4 w Ballast loss

Electrodes 92%

3 w Electrode loss

Discharge 85%

5 w Not visible or UV

Phosphor 86%

4 w UV photons lost

Quantum efficiency 45%

13 w Quantum efficiency 5.5 ev UV to 2.5 ev visible

11 w Visible light out

Losses in a 36 w t8 tri-phosphor fluorescent lamp with electronic ballast

A Sankey diagram of energy losses in a fluorescent lamp. In modern designs, the biggest loss is the quantum efficiency of converting high-energy UV photons to lower-energy visible light photons.

ing, which re-radiates the energy at longer wavelengths to emit visible light. Not all the UV energy striking the phosphor gets converted into visible light. In a modern lamp, for every 100 incident photons of UV impacting the phosphor, only 86 visible light photons are emitted (a quantum efficiency of 86%). The largest single loss in modern lamps is due to the lower energy of each photon of visible light, compared to the energy of the UV photons that generated them (a phenomenon called Stokes shift). Incident photons have an energy of 5.5 electron volts but produce visible light photons with energy around 2.5 electron volts, so only 45% of the UV energy is used; the rest is dissipated as heat. If a so-called “two-photon” phosphor could be developed, this would improve the efficiency but much research has not yet found such a system.[23]

5.2.5

Cold cathode lamps

Most fluorescent lamps use electrodes that operate by thermionic emission, meaning they are operated at a high enough temperature for the electrode material (usually aided by a special coating) to emit electrons into the tube by heat.

Cold cathode lamps are generally less efficient than thermionic emission lamps because the cathode fall voltage is much higher. The increased fall voltage results in more power dissipation at tube ends, which does not contribute to light output. However, this is less significant with longer tubes. The increased power dissipation at tube ends also usually means cold cathode tubes have to be run at a lower loading than their thermionic emission equivalents. Given the higher tube voltage required anyway, these tubes can easily be made long, and even run as series strings. They are better suited for bending into special shapes for lettering and signage, and can also be instantly switched on or off.

5.2.6 Starting The mercury atoms in the fluorescent tube must be ionized before the arc can “strike” within the tube. For small lamps, it does not take much voltage to strike the arc and starting the lamp presents no problem, but larger tubes require a substantial voltage (in the range of a thousand volts). G

B

A F

F

D C

E

A preheat fluorescent lamp circuit using an automatic starting switch. A: Fluorescent tube, B: Power (+220 volts), C: Starter, D: Switch (bi-metallic thermostat), E: Capacitor, F: Filaments, G: Ballast

However, there are also tubes that operate in cold cathode mode, whereby electrons are liberated into the tube only by the large potential difference (voltage) between the electrodes. This does not mean the electrodes are cold (indeed, they can be very hot), but it does mean they are operating below their thermionic emission temperature. Because cold cathode lamps have no thermionic emission coating to wear out they can have much longer lives than hot cathode tubes. This quality makes them desirable for maintenance-free long-life applications (such as backlights in liquid crystal displays). Sputtering of the Starting a preheat lamp. The automatic starter switch flashes electrode may still occur, but electrodes can be shaped orange each time it attempts to start the lamp. (e.g. into an internal cylinder) to capture most of the sput-

5.2. PRINCIPLES OF OPERATION Preheating This technique uses a combination filament–cathode at each end of the lamp in conjunction with a mechanical or automatic (bi-metallic) switch (see circuit diagram to the right) that initially connect the filaments in series with the ballast to preheat them; when the arc is struck the filaments are disconnected. This system is described as preheat in some countries and switchstart in others.[24] These systems are standard equipment in 200–240 V countries (and for 100–120 V lamps up to about 30 watts).

21 the tube gas by thermionic emission. In the starter, the touching contacts short out the voltage sustaining the glow discharge, extinguishing it so the gas cools down and no longer heats the bi-metallic switch, which opens within a second or two. The current through the filaments and the inductive ballast is abruptly interrupted, leaving the full line voltage applied between the filaments at the ends of the tube and generating an inductive kick which provides the high voltage needed to start the lamp. The lamp will fail to strike if the filaments are not hot enough, in which case the cycle repeats; several cycles are usually needed, which causes flickering and clicking during starting (older thermal starters behaved better in this respect). A power factor correction (PFC) capacitor draws leading current from the mains to compensate for the lagging current drawn by the lamp circuit.[24] Once the tube strikes, the impinging main discharge keeps the cathodes hot, permitting continued electron emission without the need for the filaments to continue to be heated. The starter switch does not close again because the voltage across the lit tube is insufficient to start a glow discharge in the starter.[24]

A preheat fluorescent lamp “starter” (automatic starting switch)

Before the 1960s four-pin thermal starters and manual switches were used. A method widely used for preheating from then, and still in common use, is a glow starter (illustrated). It consists of a normally open bi-metallic switch in a small sealed inert gas (neon or argon) gas-discharge lamp.

Electronic fluorescent lamp starters

With automated starters such as glow starters, a failing tube will cycle endlessly, flickering as the lamp quickly goes out because the emission mix is insufficient to keep the lamp current high enough to keep the glow starter open. This runs the ballast at higher temperature. Some more advanced starters time out in this situation, and do not attempt repeated starts until power is reset. Some older systems used a thermal over-current trip to detect repeated starting attempts and disable the circuit until manually reset. The switch contacts in glow starters are subject to wear and inevitably fail eventually, so the starter is manufactured as a plug-in replaceable unit. More recently introduced electronic starters use a different method to preheat the cathodes.[25] They may be designed to be plug-in interchangeable with glow starters for use in standard fittings. They commonly use a purposedesigned semiconductor switch and “soft start” the lamp by preheating the cathodes before applying a controlled starting pulse which strikes the lamp first time without flickering; this dislodges a minimal amount of material from the cathodes during starting, giving longer lamp life than possible with the uncontrolled impulses to which the lamp is subjected in a switchstart.[24] This is claimed to prolong lamp life by a factor of typically 3 to 4 times for a lamp frequently switched on as in domestic use,[26] and to reduce the blackening of the ends of the lamp typical of fluorescent tubes. The circuit is typically complex, but the complexity is built into the IC. Electronic starters may be optimized for fast starting (typical start time of 0.3 seconds),[26][27] or for most reliable starting even at low temperatures and with low supply voltages, with a startup time of 2–4 seconds.[28] The faster-start units may produce audible noise during start-up.[29]

When power is first applied to the circuit, there will be a glow discharge across the electrodes in the starter lamp. This heats the gas in the starter and causes one of the bi-metallic contacts to bend towards the other. When the contacts touch, the two filaments of the fluorescent lamp and the ballast will effectively be switched in series to the supply voltage. The current through the fil- Electronic starters only attempt to start a lamp for a short aments causes them to heat up and emit electrons into

22 time when power is initially applied, and do not repeatedly attempt to restrike a lamp that is dead and unable to sustain an arc; some automatically shut down a failed lamp.[25] This eliminates the re-striking of a lamp and the continuous flickering of a failing lamp with a glow starter. Electronic starters are not subject to wear and do not need replacing periodically, although they may fail like any other electronic circuit. Manufacturers typically quote lives of 20 years, or as long as the light fitting.[27][28] Starters are inexpensive, typically less than 50 US cents for the short-lived glow type (depending upon lamp power), and perhaps ten times more for the electronic type as of 2013.

CHAPTER 5. FLUORESCENT LAMP Quick-start

Quick-start ballasts use a small auto-transformer to heat the filaments when power is first applied. When an arc strikes, the filament heating power is reduced and the tube will start within half a second. The auto-transformer is either combined with the ballast or may be a separate unit. Tubes need to be mounted near an earthed metal reflector in order for them to strike. Quick-start ballasts are more common in commercial installations because of lower maintenance costs. A quick-start ballast eliminates the need for a starter switch, a common source of lamp failures. Nonetheless, Quick-start ballasts are also used in domestic (residential) installations because of the desirable feature that a Quick-start ballast light turns on Instant start nearly immediately after power is applied (when a switch is turned on). Quick-start ballasts are used only on 240 Another type of tube does not have filaments to start it V circuits and are designed for use with the older, less at all. Instant start fluorescent tubes simply use a high efficient T12 tubes. enough voltage to break down the gas and mercury column and thereby start arc conduction. These tubes can be identified by a single pin at each end of the tube. The lamp Semi-resonant start holders have a “disconnect” socket at the low-voltage end which disconnects the ballast when the tube is removed, to prevent electric shock. Low-cost lighting fixtures with an integrated electronic ballast use instant start on lamps designed for preheating, although it shortens lamp life. Rapid start Newer rapid start ballast designs provide filament power windings within the ballast; these rapidly and continuously warm the filaments/cathodes using low-voltage AC. No inductive voltage spike is produced for starting, so the lamps must be mounted near a grounded (earthed) reflector to allow the glow discharge to propagate through the tube and initiate the arc discharge. In some lamps a A 65 watt fluorescent lamp starting on a semi-resonant start cirgrounded “starting aid” strip is attached to the outside of cuit the lamp glass.

A semi-resonant start circuit diagram A rapid-start “iron” (magnetic) ballast continually heats the cathodes at the ends of the lamps. This ballast runs two F40T12 lamps in series.

The semi-resonant start circuit was invented by Thorn Lighting for use with T12 fluorescent tubes. This method uses a double wound transformer and a capacitor. With

5.2. PRINCIPLES OF OPERATION

23

no arc current, the transformer and capacitor resonate at line frequency and generate about twice the supply voltage across the tube, and a small electrode heating current.[30] This tube voltage is too low to strike the arc with cold electrodes, but as the electrodes heat up to thermionic emission temperature, the tube striking voltage falls below that of the ringing voltage, and the arc strikes. As the electrodes heat, the lamp slowly, over three to five seconds, reaches full brightness. As the arc Electronic ballast basic schematic current increases and tube voltage drops, the circuit provides current limiting. Semi-resonant start circuits are mainly restricted to use in commercial installations because of the higher initial cost of circuit components. However, there are no starter switches to be replaced and cathode damage is reduced during starting making lamps last longer, reducing maintenance costs. Due to the high open circuit tube voltage, this starting method is particularly good for starting tubes in cold locations. Additionally, the circuit power factor is almost 1.0, and no additional power factor correction is needed in the lighting installation. As the design requires that twice the supply voltage must be lower than Fluorescent lamp with an electronic ballast. the cold-cathode striking voltage (or the tubes would erroneously instant-start), this design cannot be used with 240 volt AC power unless the tubes are at least 1.5 meter length. Semi-resonant start fixtures are generally incompatible with energy saving T8 retrofit tubes, because such tubes have a higher starting voltage than T12 lamps and may not start reliably, especially in low temperatures. Recent proposals in some countries to phase out T12 tubes will reduce the application of this starting method. Programmed start This is used with electronic ballasts shown below. A programmed-start ballast is a more advanced version of rapid start. This ballast applies power to the filaments first, then after a short delay to allow the cathodes to preheat, applies voltage to the lamps to strike an arc. This ballast gives the best life and most starts from lamps, and so is preferred for applications with very frequent power cycling such as vision examination rooms and restrooms with a motion detector switch. Electronic ballasts

Electronic ballast for fluorescent lamp, 2x58W

Electronic ballasts and different compact fluorescent lamps

Electronic ballasts employ transistors to change the supply frequency into high-frequency AC while also regulating the current flow in the lamp. Some still use an inductance to limit the current, but the higher frequency allows a much smaller inductance to be used. Others use a capacitor-transistor combination to replace the inductor, since a transistor and capacitor working together can simulate the action of an inductor. These ballasts take advantage of the higher efficiency of lamps operated with higher-frequency current, which rises by almost 10% at 10 kHz, compared to efficiency at normal power frequency. When the AC period is shorter than the relaxation time to de-ionize mercury atoms in the discharge column, the discharge stays closer to optimum operating condition.[31] Electronic ballasts typically work in rapid start or instant start mode. Electronic ballasts are commonly supplied with AC power, which is internally converted to DC and then back to a variable frequency AC waveform. Depending upon the capacitance and the quality of constant-current pulse-width modulation, this can

24 largely eliminate modulation at 100 or 120 Hz. Low cost ballasts mostly contain only a simple oscillator and series resonant LC circuit. When turned on, the oscillator starts, and resonant current causes on the LC circuit. And this resonant current directly drive the switching transistor through the ring core transformer. This principle is called the current resonant inverter circuit. After a short time the voltage across the lamp reaches about 1 kV and the lamp ignites. The process is too fast to preheat the cathodes, so the lamp instant-starts in cold cathode mode. The cathode filaments are still used for protection of the ballast from overheating if the lamp does not ignite. A few manufacturers use positive temperature coefficient (PTC) thermistors to disable instant starting and give some time to preheat the filaments.

CHAPTER 5. FLUORESCENT LAMP

5.2.7 End of life The end of life failure mode for fluorescent lamps varies depending on how they are used and their control gear type. Often the light will turn pink (see Loss of mercury) with black burns on the ends of the lamp due to sputtering of emission mix (see below). The lamp may also flicker at a noticeable rate (see Flicker problems). More information about normal failure modes are as follows: Emission mix

More complex electronic ballasts use programmed start. The output frequency is started above the resonance frequency of the output circuit of the ballast; and after the filaments are heated, the frequency is rapidly decreased. If the frequency approaches the resonant frequency of the ballast, the output voltage will increase so much that the lamp will ignite. If the lamp does not ignite, an electronic circuit stops the operation of the ballast. Many electronic ballasts are controlled by a microcontroller or similar, and these are sometimes called digital ballasts. Digital ballasts can apply quite complex logic to lamp starting and operation. This enables functions such as testing for broken electrodes and missing tubes before attempting to start, auto detect tube replacement, and auto detection of tube type, such that a single ballast can be used with several different tubes, even those that operate at different arc currents, etc. Once such fine grained control over the starting and arc current is achievable, features such as dimming, and having the ballast maintain a constant light level against changing sunlight contribution are all easily included in the embedded microcontroller software, and can be found in various manufacturers’ products. Since introduction in the 1990s, high-frequency ballasts have been used in general lighting fixtures with either rapid start or pre-heat lamps. These ballasts convert the incoming power to an output frequency in excess of 20 kHz. This increases lamp efficiency. These are used in several applications, including new generation tanning lamp systems, whereby a 100 watt lamp (e.g., F71T12BP) can be lit using 90 watts of actual power while obtaining the same luminous flux (measured in lumens) as magnetic ballasts.[32] These ballasts operate with voltages that can be almost 600 volts, requiring some consideration in housing design, and can cause a minor limitation in the length of the wire leads from the ballast to the lamp ends.

Closeup of the filament on a low pressure mercury gas discharge lamp showing white thermionic emission mix coating on the central portion of the coil acting as hot cathode. Typically made of a mixture of barium, strontium and calcium oxides, the coating is sputtered away through normal use, often eventually resulting in lamp failure.

The "emission mix" on the lamp filaments/cathodes is required to enable electrons to pass into the gas via thermionic emission at the lamp operating voltages used. The mix is slowly sputtered off by bombardment with electrons and mercury ions during operation, but a larger amount is sputtered off each time the lamp is started with cold cathodes. The method of starting the lamp has a significant impact on this. Lamps operated for typically less than 3 hours each switch-on will normally run out of the emission mix before other parts of the lamp fail. The sputtered emission mix forms the dark marks at the lamp ends seen in old lamps. When all the emission mix is gone, the cathode cannot pass sufficient electrons into the gas fill to maintain the gas discharge at the designed lamp operating voltage. Ideally, the control gear should shut down the lamp when this happens. However, due to cost, negative differential resistance and sometimes high starting voltage, some control gear will provide sufficient increased operating voltage to continue lighting the lamp in cold cathode mode. This will cause overheating of the lamp end and rapid disintegration of the electrodes (fila-

5.3. PHOSPHORS AND THE SPECTRUM OF EMITTED LIGHT

25

ment goes open-circuit) and filament support wires until initially causes an extended run-up time to full light outthey are completely gone or the glass cracks, wrecking put, and finally causes the lamp to glow a dim pink when the low pressure gas fill and stopping the gas discharge. the mercury runs out and the argon base gas takes over as the primary discharge.[33] Ballast electronics This may occur in compact fluorescent lamps with integral electrical ballasts or in linear lamps. Ballast electronics failure is a somewhat random process that follows the standard failure profile for any electronic device. There is an initial small peak of early failures, followed by a drop and steady increase over lamp life. Life of electronics is heavily dependent on operating temperature—it typically halves for each 10 °C temperature rise. The quoted average life of a lamp is usually at 25 °C (77 °F) ambient (this may vary by country). The average life of the electronics at this temperature is normally greater than this, so at this temperature, not many lamps will fail due to failure of the electronics. In some fittings, the ambient temperature could be well above this, in which case failure of the electronics may become the predominant failure mechanism. Similarly, running a compact fluorescent lamp base-up will result in hotter electronics, which can cause shorter average life (particularly with higher power rated ones). Electronic ballasts should be designed to shut down the tube when the emission mix runs out as described above. In the case of integral electronic ballasts, since they never have to work again, this is sometimes done by having them deliberately burn out some component to permanently cease operation.

Subjecting the tube to asymmetric waveforms, where the total current flow through the tube does not cancel out and the tube effectively operates under a DC bias, causes asymmetric distribution of mercury ions along the tube due to cataphoresis. The localized depletion of mercury vapor pressure manifests as pink luminescence of the base gas in the vicinity of one of the electrodes, and the operating lifetime of the lamp may be dramatically shortened. This can be an issue with some poorly designed inverters.[34]

Burned filaments

The filaments can burn at the end of the lamp’s lifetime, opening the circuit and losing the capability to heat up. Both filaments lose function as they are connected in series, with just a simple switch start circuit a broken filament will render the lamp completely useless. Filaments rarely burn or fail open circuit unless the filament becomes depleted of emitter and the control gear is able to supply a high enough voltage across the tube to operate it in cold cathode mode. Some digital electronic ballasts are capable of detecting broken filaments and can still strike an arc with one or both filaments broken providing there is still sufficient emitter. A broken filament in a lamp attached to a magnetic ballast often causes both lamps to In most CFLs the filaments are connected in series, with a burn out or flicker. small capacitor between them. The discharge, once lit, is in parallel to the capacitor and presents a lower-resistance path, effectively shorting the capacitor out. Phosphor

5.3 Phosphors and the spectrum of emitted light

The phosphor drops off in efficiency during use. By around 25,000 operating hours, it will typically be half the brightness of a new lamp (although some manufacturers claim much longer half-lives for their lamps). Lamps that do not suffer failures of the emission mix or integral ballast electronics will eventually develop this failure mode. They still work, but have become dim and inefficient. The process is slow, and often becomes obvious only when a new lamp is operating next to an old one. Loss of mercury As in all mercury-based gas-filled tubes, mercury is slowly adsorbed into the glass, phosphor, and tube electrodes throughout the life of the lamp, until it can no longer function. Newer lamps have just enough mercury to last the expected life of the lamp. Loss of mercury will take over from failure of the phosphor in some lamps. The failure symptoms are similar, except loss of mercury

Light from a fluorescent tube lamp reflected by a CD shows the individual bands of color.

The spectrum of light emitted from a fluorescent lamp is the combination of light directly emitted by the mercury vapor, and light emitted by the phosphorescent coating. The spectral lines from the mercury emission and

26

CHAPTER 5. FLUORESCENT LAMP

the phosphorescence effect give a combined spectral distribution of light that is different from those produced by incandescent sources. The relative intensity of light emitted in each narrow band of wavelengths over the visible spectrum is in different proportions compared to that of an incandescent source. Colored objects are perceived differently under light sources with differing spectral distributions. For example, some people find the color rendition produced by some fluorescent lamps to be harsh and displeasing. A healthy person can sometimes appear to have an unhealthy skin tone under fluorescent lighting. The extent to which this phenomenon occurs is related to the light’s spectral composition, and may be gauged by its color rendering index (CRI). A helical cool-white fluorescent lamp reflected in a diffraction grating reveals the various spectral lines which make up the light.

5.3.1

Color temperature

5500K

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4200K

4000K

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8000K

Kelvin Temperature Chart

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3200K

3000K

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2700K

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Main article: Color temperature Correlated color temperature (CCT) is a measure of the

The color temperature of different electric lamps

“shade” of whiteness of a light source compared with a blackbody. Typical incandescent lighting is 2700 K, which is yellowish-white. Halogen lighting is 3000 K. Fluorescent lamps are manufactured to a chosen CCT by altering the mixture of phosphors inside the tube. Warmwhite fluorescents have CCT of 2700 K and are popular for residential lighting. Neutral-white fluorescents have a CCT of 3000 K or 3500 K. Cool-white fluorescents have a CCT of 4100 K and are popular for office lighting. Daylight fluorescents have a CCT of 5000 K to 6500 K, which is bluish-white. High CCT lighting generally requires higher light levels. At dimmer illumination levels, the human eye perceives lower color temperatures as more pleasant, as related through the Kruithof curve. So, a dim 2700 K incandescent lamp appears comfortable and a bright 5000 K lamp also appears natural, but a dim 5000 K fluorescent lamp appears too pale. Daylight-type fluorescents look natural only if they are very bright.

5.3.2

Color rendering index

Fluorescent spectra in comparison with other forms of lighting. Clockwise from upper left: Fluorescent lamp, incandescent bulb, candle flame and LED lighting.

colors can be perceived using light from a source, relative to light from a reference source such as daylight or a blackbody of the same color temperature. By definition, an incandescent lamp has a CRI of 100. Real-life fluorescent tubes achieve CRIs of anywhere from 50 to 99. Fluorescent lamps with low CRI have phosphors that emit too little red light. Skin appears less pink, and hence “unhealthy” compared with incandescent lighting. Colored objects appear muted. For example, a low CRI 6800 K halophosphate tube (an extreme example) will make reds appear dull red or even brown. Since the eye is relatively less efficient at detecting red light, an improvement in color rendering index, with increased energy in the red part of the spectrum, may reduce the overall luminous efficacy.[35]

Lighting arrangements use fluorescent tubes in an assortment of tints of white. Sometimes this is because of the Main article: Color rendering index lack of appreciation for the difference or importance of differing tube types. Mixing tube types within fittings can Color rendering index (CRI) is a measure of how well improve the color reproduction of lower quality tubes.

5.5. ADVANTAGES

5.3.3

Phosphor composition

27 LEDs are sometimes even more efficient and are more rapidly increasing in efficiency. A typical 100 watt tungsten filament incandescent lamp may convert only 5% of its power input to visible white light (400–700 nm wavelength), whereas typical fluorescent lamps convert about 22% of the power input to visible white light.[36]

Some of the least pleasant light comes from tubes containing the older, halophosphate-type phosphors (chemical formula Ca5 (PO4 )3 (F, Cl):Sb3+ , Mn2+ ). This phosphor mainly emits yellow and blue light, and relatively little green and red. In the absence of a reference, this The efficacy of fluorescent tubes ranges from about 16 mixture appears white to the eye, but the light has an in- lumens per watt for a 4 watt tube with an ordinary ballast complete spectrum. The CRI of such lamps is around 60. to over 100 lumens per watt[37] with a modern electronic Since the 1990s, higher quality fluorescent lamps use ei- ballast, commonly averaging 50 to 67 lm/W overall. Most ther a higher CRI halophosphate coating, or a triphos- compact fluorescents above 13 watts with integral elecphor mixture, based on europium and terbium ions, that tronic ballasts achieve about 60 lm/W. Lamps are rated have emission bands more evenly distributed over the by lumens after 100 hours of operation.[38] For a given spectrum of visible light. High CRI halophosphate and fluorescent tube, a high-frequency electronic ballast gives triphosphor tubes give a more natural color reproduction about a 10% efficacy improvement over an inductive balto the human eye. The CRI of such lamps is typically last. It is necessary to include the ballast loss when evaluating the efficacy of a fluorescent lamp system; this can 82–100. be about 25% of the lamp power with magnetic ballasts, and around 10% with electronic ballasts.

5.4 Applications Fluorescent lamps come in many shapes and sizes. The compact fluorescent lamp (CFL) is becoming more popular. Many compact fluorescent lamps integrate the auxiliary electronics into the base of the lamp, allowing them to fit into a regular light bulb socket. In US residences, fluorescent lamps are mostly found in kitchens, basements, or garages, but schools and businesses find the cost savings of fluorescent lamps to be significant and rarely use incandescent lights. Tax incentives and building codes result in higher use in places such as California.

Fluorescent lamp efficacy is dependent on lamp temperature at the coldest part of the lamp. In T8 lamps this is in the center of the tube. In T5 lamps this is at the end of the tube with the text stamped on it. The ideal temperature for a T8 lamp is 25 °C (77 °F) while the T5 lamp is ideally at 35 °C (95 °F).

5.5.2 Life

Typically a fluorescent lamp will last 10 to 20 times as long as an equivalent incandescent lamp when operated several hours at a time. Under standard test conditions general lighting lamps have 9,000 hours or longer service In other countries, residential use of fluorescent lighting life.[39] varies depending on the price of energy, financial and en- The higher initial cost of a fluorescent lamp compared vironmental concerns of the local population, and accept- with an incandescent lamp is usually more than compenability of the light output. In East and Southeast Asia it is sated for by lower energy consumption over its life.[40] very rare to see incandescent bulbs in buildings anywhere. A few manufacturers are producing T8 lamps with 90,000 Some countries are encouraging the phase-out of incan- hour lamp lives, rivalling the life of LED lamps. descent light bulbs and substitution of incandescent lamps with fluorescent lamps or other types of energy-efficient lamps. 5.5.3 Lower luminance In addition to general lighting, special fluorescent lights are often used in stage lighting for film and video production. They are cooler than traditional halogen light sources, and use high-frequency ballasts to prevent video flickering and high color-rendition index lamps to approximate daylight color temperatures.

Compared with an incandescent lamp, a fluorescent tube is a more diffuse and physically larger light source. In suitably designed lamps, light can be more evenly distributed without point source of glare such as seen from an undiffused incandescent filament; the lamp is large compared to the typical distance between lamp and illuminated surfaces.

5.5 Advantages 5.5.4 Lower heat 5.5.1

Luminous efficacy

Fluorescent lamps give off about one-fifth the heat of Fluorescent lamps convert more of the input power to equivalent incandescent lamps. This greatly reduces the visible light than incandescent lamps, though as of 2013 size, cost, and energy consumption devoted to air con-

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CHAPTER 5. FLUORESCENT LAMP

ditioning for office buildings that would typically have health problems relating to light sensitivity that is aggramany lights and few windows. vated by artificial lighting.

5.6 Disadvantages 5.6.1

Frequent switching

The ultraviolet light from a fluorescent lamp can degrade the pigments in paintings (especially watercolor pigments) and bleach the dyes used in textiles and some printing. Valuable art work must be protected from ultraviolet light by placing additional glass or transparent acrylic sheets between the lamp and the art work.

If the lamp is installed where it is frequently switched on and off, it will age rapidly.[41] Under extreme conditions, its lifespan may be much shorter than a cheap incandes- 5.6.4 cent lamp. Each start cycle slightly erodes the electronemitting surface of the cathodes; when all the emission material is gone, the lamp cannot start with the available ballast voltage. Fixtures intended for flashing of lights (such as for advertising) will use a ballast that maintains cathode temperature when the arc is off, preserving the life of the lamp.

Ballast

The extra energy used to start a fluorescent lamp is equivalent to a few seconds of normal operation; it is more energy-efficient to switch off lamps when not required for several minutes.[42][43]

5.6.2

Health and safety issues

Main article: Fluorescent lamps and health If a fluorescent lamp is broken, a very small amount of mercury can contaminate the surrounding environment. About 99% of the mercury is typically contained in the phosphor, especially on lamps that are near the end of their life.[44] The broken glass is usually considered a greater hazard than the small amount of spilled mercury. The EPA recommends airing out the location of a fluorescent tube break and using wet paper towels to help pick up the broken glass and fine particles. Any glass and used towels should be disposed of in a sealed plastic bag. Vacuum cleaners can cause the particles to become airborne, and should not be used.[45] Fluorescent lamps with magnetic ballasts flicker at a normally unnoticeable frequency of 100 or 120 Hz and this flickering can cause problems for some individuals with light sensitivity,[46] they are listed as problematic for some individuals with autism, epilepsy,[47] lupus,[48] chronic fatigue syndrome, Lyme disease,[49] and vertigo.[50] Newer fluorescent lights without magnetic ballasts have essentially eliminated flicker.[51]

5.6.3

Ultraviolet emission

Fluorescent lamps emit a small amount of ultraviolet (UV) light. A 1993 study in the US found that ultraviolet exposure from sitting under fluorescent lights for eight hours is equivalent to only one minute of sun exposure.[52] Very sensitive individuals may experience a variety of

Magnetic single-lamp ballasts have a low power factor.

Fluorescent lamps require a ballast to stabilize the current through the lamp, and to provide the initial striking voltage required to start the arc discharge. This increases the cost of fluorescent light fixtures, though often one ballast is shared between two or more lamps. Electromagnetic ballasts with a minor fault can produce an audible humming or buzzing noise. Magnetic ballasts are usually filled with a tar-like potting compound to reduce emitted noise. Hum is eliminated in lamps with a high-frequency electronic ballast. Energy lost in magnetic ballasts was around 10% of lamp input power according to GE literature from 1978.[21] Electronic ballasts reduce this loss.

5.6.5 Power quality and radio interference Simple inductive fluorescent lamp ballasts have a power factor of less than unity. Inductive ballasts include power factor correction capacitors. Simple electronic ballasts may also have low power factor due to their rectifier input stage. Fluorescent lamps are a non-linear load and generate harmonic currents in the electrical power supply. The arc within the lamp may generate radio frequency noise, which can be conducted through power wiring. Suppression of radio interference is possible. Very good suppression is possible, but adds to the cost of the fluorescent fixtures.

5.6. DISADVANTAGES

5.6.6

29

Operating temperature

lamps operating on a lead-lag ballast. Unlike a true strobe lamp, the light level drops in appreciable time and so subFluorescent lamps operate best around room temper- stantial “blurring” of the moving part would be evident. ature. At much lower or higher temperatures, effiIn some circumstances, fluorescent lamps operated at the ciency decreases. At below-freezing temperatures stanpower supply frequency (50 or 60 Hz) can also produce dard lamps may not start. Special lamps may be needed flicker at the same frequency itself, which is noticeable for reliable service outdoors in cold weather. In appliby more people. This can happen in the last few hours cations such as road and railway signalling, fluorescent of tube life when the cathode emission coating at one end lamps which do not generate as much heat as incandeshas almost run out, and that cathode starts having difficent lamps may not melt snow and ice build up around culty emitting enough electrons into the gas fill, resultthe lamp, leading to reduced visibility. ing in slight rectification and hence uneven light output in positive and negative going AC cycles. Power frequency flicker can also sometimes be emitted from the very ends 5.6.7 Lamp shape of the tubes, if each tube electrode produces a slightly Fluorescent tubes are long, low-luminance sources com- different light output pattern on each half-cycle. Flicker pared with high pressure arc lamps, incandescent lamps at power frequency is more noticeable in the peripheral and LEDs. However, low luminous intensity of the emit- vision than it is when viewed directly, as is all flicker ting surface is useful because it reduces glare. Lamp fix- (since the peripheral vision is faster—has a higher critture design must control light from a long tube instead of ical frequency—than the central vision). a compact globe. The compact fluorescent lamp (CFL) replaces regular incandescent bulbs. However, some CFLs will not fit some lamps, because the harp (heavy wire shade support bracket) is shaped for the narrow neck of an incandescent lamp, while CFLs tend to have a wide housing for their electronic ballast close to the lamp’s base.

5.6.8

Near the end of life, fluorescent lamps can start flickering at a frequency lower than the power frequency. This is due to a dynamic instability inherent in the negative resistance of the plasma source,[54] which can be from a bad lamp, a bad ballast, or a bad starter; or occasionally from a poor connection to power.

Flicker problems

The “beat effect” problem created when shooting films under standard fluorescent lighting

The “beat effect” problem created when shooting photos under standard fluorescent lighting

Fluorescent lamps using a magnetic power line frequency ballast do not give out a steady light; instead, they flicker at twice the supply frequency. This results in fluctuations not only with light output but color temperature as well,[53] which may pose problems for photography and people who are sensitive to the flicker. Even among persons not sensitive to light flicker, a stroboscopic effect can be noticed, where something spinning at just the right speed may appear stationary if illuminated solely by a single fluorescent lamp. This effect is eliminated by paired

New fluorescent lamps may show a twisting spiral pattern of light in a part of the lamp. This effect is due to loose cathode material and usually disappears after a few hours of operation.[55] Electromagnetic ballasts may also cause problems for video recording as there can be a “beat effect” between the periodic reading of a camera’s sensor and the fluctuations in intensity of the fluorescent lamp. Fluorescent lamps using high-frequency electronic ballasts do not produce visible light flicker, since above about 5 kHz, the excited electron state half-life is longer than a half cycle, and light production becomes continuous. Operating frequencies of electronic ballasts are selected to avoid interference with infrared remote controls.

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CHAPTER 5. FLUORESCENT LAMP

Poor quality (or failing) electronic ballasts may have insufficient reservoir capacitance or have poor regulation, thereby producing considerable 100/120 Hz modulation of the light.

5.6.9

Dimming

urine and certain dyes that would be invisible in visible light) as well as to attract insects to bug zappers. So-called blacklite blue lamps are also made from more expensive deep purple glass known as Wood’s glass rather than clear glass. The deep purple glass filters out most of the visible colors of light directly emitted by the mercury-vapor discharge, producing proportionally less visible light compared with UV light. This allows UV-induced fluorescence to be seen more easily (thereby allowing blacklight posters to seem much more dramatic). The blacklight lamps used in bug zappers do not require this refinement so it is usually omitted in the interest of cost; they are called simply blacklite (and not blacklite blue).

Fluorescent light fixtures cannot be connected to dimmer switches intended for incandescent lamps. Two effects are responsible for this: the waveform of the voltage emitted by a standard phase-control dimmer interacts badly with many ballasts, and it becomes difficult to sustain an arc in the fluorescent tube at low power levels. Dimming installations require a compatible dimming ballast. These systems keep the cathodes of the fluorescent tube Tanning lamps The lamps used in tanning beds confully heated even as the arc current is reduced, promoting tain a different phosphor blend (typically 3 to 5 or easy thermionic emission of electrons into the arc stream. more phosphors) that emits both UVA and UVB, CFLs are available that work in conjunction with a suitprovoking a tanning response in most human skin. able dimmer. Typically, the output is rated as 3% to 10% UVB (5% most typical) with the remaining UV as UVA. These are mainly F71, F72 or F73 HO (100 W) 5.6.10 Disposal and recycling lamps, although 160 W VHO are somewhat common. One common phosphor used in these lamps Main article: Fluorescent lamp recycling is lead-activated barium disilicate, but a europiumactivated strontium fluoroborate is also used. Early lamps used thallium as an activator, but emissions The disposal of phosphor and particularly the toxic of thallium during manufacture were toxic.[59] mercury in the tubes is an environmental issue. Governmental regulations in many areas require special disposal UVB Medical lamps The lamps used in Phototherapy of fluorescent lamps separate from general and household contain a phosphor that emits only UVB Ultraviowastes. For large commercial or industrial users of fluolet light. There are two types: Broadband UVB that rescent lights, recycling services are available in many nagives 290-320 nanometer with peak wavelength of tions, and may be required by regulation.[56][57] In some 306nm, and Narrowband UVB that gives 311-313 areas, recycling is also available to consumers.[58] nanometer. Due to its longer wavelength the Narrowband UVB requires a 10 times higher dose to the skin, compared to the broadband. The Narrowband is good for Psoriasis, Eczema (Atopic Dermatitis). 5.7 Lamp sizes and designations Vitiligo, Lichen Planus and some other skin diseases. The Broadband is better for increasing ViMain article: Fluorescent lamp formats tamin D3 in the body. Systematic nomenclature identifies mass-market lamps as Grow lamps Grow lamps contain phosphor blends that encourage photosynthesis, growth, or flowering in to general shape, power rating, length, color, and other plants, algae, photosynthetic bacteria, and other electrical and illuminating characteristics. light-dependent organisms. These often emit light in the red and blue color range, which is absorbed by chlorophyll and used for photosynthesis in plants.[60]

5.8 Other fluorescent lamps

Infrared lamps Lamps can be made with a lithium metaluminate phosphor activated with iron. This Black lights Blacklights are a subset of fluorescent phosphor has peak emissions between 675 and 875 lamps that are used to provide near ultraviolet light nanometers, with lesser emissions in the deep red (at about 360 nm wavelength). They are built in the part of the visible spectrum.[61] same fashion as conventional fluorescent lamps but the glass tube is coated with a phosphor that converts Bilirubin lamps Deep blue light generated from a europium-activated phosphor is used in the light the short-wave UV within the tube to long-wave UV therapy treatment of jaundice; light of this color rather than to visible light. They are used to propenetrates skin and helps in the breakup of excess voke fluorescence (to provide dramatic effects usbilirubin.[19] ing blacklight paint and to detect materials such as

5.10. SEE ALSO

31

Germicidal lamps Germicidal lamps depend on the property that spectrum of 254 nm kills most germs. Germicidal lamps contain no phosphor at all (making them mercury vapor gas discharge lamps rather than fluorescent) and their tubes are made of fused quartz that is transparent to the UV light emitted by the mercury discharge. The 254 nm UV emitted by these tubes will kill germs and ionize oxygen to ozone. In addition it can cause eye and skin damage and should not be used or observed without eye and skin protection. Besides their uses to kill germs and create ozone, they are sometimes used by geologists to identify certain species of minerals by the color of their fluorescence. When used in this fashion, they are fitted with filters in the same way as blacklightblue lamps are; the filter passes the short-wave UV and blocks the visible light produced by the mercury discharge. They are also used in some EPROM erasers. Germicidal lamps have designations beginning with G (meaning 'Germicidal'), rather than F, for example G30T8 for a 30-watt, 1-inch (2.5 cm) diameter, 36inch (91 cm) long germicidal lamp (as opposed to Capacitive coupling with high-voltage power lines can light a an F30T8, which would be the fluorescent lamp of lamp continuously at low intensity. the same size and rating). Also, placing a fluorescent lamp half way up a two-way Electrodeless lamps Electrodeless induction lamps are radio antenna while transmitting will illuminate the lamp fluorescent lamps without internal electrodes. They due to the RF energy. have been commercially available since 1990. A current is induced into the gas column using electromagnetic induction. Because the electrodes are usually the life-limiting element of fluorescent 5.10 See also lamps, such electrodeless lamps can have a very long • Compact fluorescent lamp service life, although they also have a higher purchase price. • Fluorescent lamp formats Cold-cathode fluorescent lamps (CCFL) Coldcathode fluorescent lamps are used as backlighting for LCD displays in personal computer and TV monitors. They are also popular with computer case modders in recent years.

5.9 Science demonstrations Fluorescent lamps can be illuminated by means other than a proper electrical connection. These other methods, however, result in very dim or very short-lived illumination, and so are seen mostly in science demonstrations. Static electricity or a Van de Graaff generator will cause a lamp to flash momentarily as it discharges a high voltage capacitance. A Tesla coil will pass high-frequency current through the tube, and since it has a high voltage as well, the gases within the tube will ionize and emit light. Capacitive coupling with high-voltage power lines can light a lamp continuously at low intensity, depending on the intensity of the electrostatic field.

• Fluorescent lamp recycling • Fluorescent lamps and health • Metal halide lamp • List of light sources • Gas filled tube

5.11 References [1] HTTP 404 Error Message - WA State Dept. of Ecology [2] M. A. Laughton Electrical Engineer’s Reference Book Sixteenth Edition, Newnes, 2003 ISBN 0-7506-4637-3, page 21-12 [3] Mercury-Containing Light Bulb (Lamp) Recycling | Universal Waste | US EPA [4] Gribben, John; “The Scientists; A History of Science Told Through the Lives of Its Greatest Inventors"; Random House; 2004; pp 424–432; ISBN 978-0-8129-6788-3

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[5] See Bright 1949, pp. 381–385 for discussion of early history [6] US 865367 Fluorescent Electric Lamp [7] “Mr. Moore’s Etheric Light. The Young Newark Electrician’s New And Successful Device.”. New York Times. October 2, 1896. Retrieved 2008-05-26. Paid access. [8] Gaster, Leon; Dow, John Stewart (1915). Modern illuminants and illuminating engineering. Whittaker & Co. pp. 107–111. [9] Bright, Arthur A., Jr. (1949). The Electric-Lamp Industry. MacMillan. Pages 221–223 describe Moore tubes. Pages 369–374 describe neon tube lighting. Page 385 discusses Risler’s contributions to fluorescent coatings in the 1920s. Pages 388–391 discuss the development of the commercial fluorescent at General Electric in the 1930s. [10] Weeks, Mary Elvira (2003). Discovery of the Elements: Third Edition (reprint). Kessinger Publishing. p. 287. ISBN 978-0-7661-3872-8. [11] Claude, Georges (November 1913). “The Development of Neon Tubes”. The Engineering Magazine: 271–274.

CHAPTER 5. FLUORESCENT LAMP

[23] pages 196–197 [24] Philips Semiconductor: Power Semiconductor Applications - Lighting, p579 [25] Datasheet of typical electronic starter (not fast start), with detailed explanation of operation [26] Datasheet of typical fast start electronic starter, with detailed explanation of operation [27] Data on an ultrafast starter, with nominal startup time of 0.3 seconds [28] Data on a typical starter for even adverse conditions, with nominal startup time of 2.4 seconds [29] Quick Start for Fluorescent Lights “All three of the 'FAST' (< .5 seconds) starter brands caused an audible 'BURRRRRRRP' noise in some light fittings as they started and this is an inherent problem caused by their use of the faster 'DC' heating. It is worse with higher wattage tubes and if there is any loose metal in the light fitting.” [30] Thorn Lighting Technical Handbook [31] page 182

[12] van Dulken, Stephen (2002). Inventing the 20th century: 100 inventions that shaped the world : from the airplane to the zipper. New York University Press. p. 42. ISBN 978-0-8147-8812-7.

[32] “Energy Conservation Standards for Fluorescent Lamp Ballasts” (PDF). US Department of Energy. p. 31. Retrieved 29 January 2012.

[13] US patent 1790153, Albert W. Hull, “Electrical Discharge Device and Method of Operation”, issued 193101-27, assigned to General Electric Company

[33]

[14] US patent 2182732, Friedrich Meyer; Hans-Joachim Spanner & Edmund Germer, “Metal Vapor Lamp”, issued 1939-12-05, assigned to General Electric Company

[35] page 8

[34] http://www.htl.co.jp/img/p_pro4_p10.pdf

[36] page 20

[15] Lighting A Revolution: 20th Century Store-room

[37] Panasonic. “Panasonic Spiral Fluorescent ceiling lights, 124.3lm/W”. Retrieved 2010-09-27.

[16] Kane, Raymond; Sell, Heinz (2001). “A Review of Early Inorganic Phosphors”. Revolution in lamps: a chronicle of 50 years of progress. p. 98. ISBN 978-0-88173-378-5.

[38] Klipstein, Donald L. “Light and Lighting Facts and Bits of Data!". Retrieved 2007-12-29.

[17] William M. Yen, Shigeo Shionoya, Hajime Yamamoto, Practical Applications of Phosphors,CRC Press, 2006, ISBN 1-4200-4369-2, pages 84-85

[39] Fink, Donald G.; Beaty, H. Wayne, eds. (1978). Standard Handbook for Electrical Engineers (11th ed.). McGraw Hill. pp. 22–17. ISBN 978-0-070-20974-9.

[18] Kulshreshtha, Alok K. (2009). Basic Electrical Engineering: Principles and Applications. India: Tata McGrawHill Education. p. 801. ISBN 0-07-014100-2. The partial pressure of the mercury vapor alone is about 0.8 Pa (8 millionths of atmospheric pressure), in a T12 40-watt lamp. See Kane and Sell, 2001, page 185

[40] National Research Council (U.S.). Building Research Institute. Building illumination: the effect of new lighting levels Publisher National Academies, 1959. Page 81 [41] “Compact Fluorescent Lighting” (PDF). eere.energy.gov. Archived from the original (PDF) on May 11, 2011. Retrieved 24 July 2012.

[19] Van Broekhoven, Jacob (2001). “Chapter 5: Lamp Phosphors”. In Kane, Raymond; Sell, Heinz. Revolution in lamps: a chronicle of 50 years of progress (2nd ed.). The Fairmont Press, Inc. p. 93. ISBN 0-88173-378-4.

[42] “Science Fact or Science Fiction: Fluorescent Lights”. Quirks and Quarks (CBC). Archived from the original on October 28, 2011. Retrieved 27 October 2011.

[20] T12 specifies the bulb’s diameter in 1/8 inch units; a T12 bulb is 12×(1/8) inches or 1.5 in (38 mm) in diameter.

[43] “When to Turn Off Your Lights”. U.S. Department of Energy. U.S. Department of Energy. Retrieved 28 November 2012.

[21] General Electric, Fluorescent Lamps Technical Bulletin TP 111R, December 1978 pages 10–11 [22] page 188

[44] Floyd, et al. (2002), quoted on page 184 of Toolkit for identification and quantification of mercury releases (PDF)

5.13. EXTERNAL LINKS

[45] Fluorescent lamp cleanup Accessed 22 Apr 2009. [46] “Working with Light Sensitivity”. [47] “Accommodation Ideas for Employees with Epilepsy”. [48] “Accommodation and Compliance Series: Employees with Lupus”. [49] Shadick NA, Phillips CB, Sangha O et al. (December 1999). “Musculoskeletal and neurologic outcomes in patients with previously treated Lyme disease”. Ann. Intern. Med. 131 (12): 919–26. doi:10.7326/0003-4819-13112-199912210-00003. PMID 10610642. [50] “Accommodating People with Vertigo”. [51] Lighting flicker, retrieved 2010 April 19 [52] Lytle, CD; Cyr, WH; Beer, JZ; Miller, SA; James, RH; Landry, RJ; Jacobs, ME; Kaczmarek, RG; Sharkness, CM; Gaylor, D et al. (December 1993). “An Estimation of Squamous Cell Carcinoma Risk from Ultraviolet Radiation Emitted by Fluorescent Lamps”. Photodermatol Photoimmunol Photomed 9 (6): 268–74. PMID 1343229. [53] “Exposure and Color Temperature Variations When Photographing Under Fluorescent Lights” [54] Glozman, Stanislav; Ben-Yaakov, Shmuel (September– October 2001). “Dynamic Interaction Analysis of HF Ballasts and Fluorescent Lamps Based on Envelope Simulation”. IEEE Transactions on Industry Applications 37 (5): 1531–1536. doi:10.1109/28.952531. [55] page 22 [56] LampRecycle.org Commercial Lighting: Lamp Recyclers [57] EPA.gov Mercury-Containing Light Bulb (Lamp) Regulatory Framework [58] EPA.gov Mercury-Containing Light Bulb (Lamp) Collection and Recycling Programs Where You Live [59] page 120 [60] Goins, GD and Yorio, NC and Sanwo, MM and Brown, CS (1997). “Photomorphogenesis, photosynthesis, and seed yield of wheat plants grown under red light-emitting diodes (LEDs) with and without supplemental blue lighting”. Journal of Experimental Botany (Soc Experiment Biol) 48 (7): 1407–1413. doi:10.1093/jxb/48.7.1407. [61] pg. 122

5.12 Further reading • Bright, Arthur Aaron (1949). The Electric-Lamp Industry: Technological Change and Economic Development from 1800 to 1947. Macmillan Co. • Emanuel Gluskin, “The fluorescent lamp circuit”, (Circuits & Systems Expositions) • IEEE Transactions on Circuits and Systems, Part I: Fundamental Theory and Applications 46(5), 1999 (529-544).

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5.13 External links • Popular Science, January 1940 Fluorescent Lamps • T5 Fluorescent Systems — Lighting Research Center Research about the improved T5 relative to the previous T8 standard • NASA: The Fluorescent Lamp: A plasma you can use • How Fluorescent Tubes are Manufactured on YouTube • Museum of Electric Lamp Technology • R. N. Thayer (1991-10-25). “The Fluorescent Lamp: Early U. S. Development”. The Report courtesy of General Electric Company. Retrieved 200703-18. • Wiebe E. Bijker,Of bicycles, bakelites, and bulbs: toward a theory of sociotechnical change MIT Press, 1995, Chapter 4, preview available at Google Books, on the social construction of fluorescent lighting • Explanations and schematics of some fluorescent lamps

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5.14 Text and image sources, contributors, and licenses 5.14.1

Text

• Electric arc Source: http://en.wikipedia.org/wiki/Electric%20arc?oldid=651897329 Contributors: Bdesham, Glenn, Hike395, Hcobin, Omegatron, Pengo, Wjbeaty, Giftlite, BenFrantzDale, Art Carlson, Nielmo~enwiki, Rick Burns, Deglr6328, Pt, Bert Hickman, Zippanova, Batmanand, Wtshymanski, Skatebiker, DV8 2XL, Gene Nygaard, Thryduulf, Pol098, Julo, Isnow, Palica, Nightscream, Ceinturion, Sango123, Old Moonraker, Nihiltres, Fragglet, CJLL Wright, YurikBot, FrenchIsAwesome, Shaddack, Kkmurray, Cyrus Grisham, Cmglee, Amit A., Bluebot, Avin, In The Mindway, Lejzy, Minipie8, Dogears, KLLvr283, Waggers, DabMachine, Iridescent, Tawkerbot2, Chetvorno, Ctudorpole, Thijs!bot, Leon7, Andante1980, AntiVandalBot, El floz, JAnDbot, Oldengaerde, Photodude, Glrx, R'n'B, Nigholith, Yonidebot, Mike.lifeguard, Katalaveno, Btd, Squids and Chips, VolkovBot, Hsilamot, Jacob Lundberg, Mahogny, AlleborgoBot, Biscuittin, SieBot, ScAvenger lv, Steven Zhang, OKBot, Alexei gerasimov, Nergaal, Muhends, GorillaWarfare, Mild Bill Hiccup, Lbelkind, Alexbot, Darius Clark~enwiki, Thingg, DumZiBoT, ZooFari, Alex Khimich, Addbot, Chamberlain2007, Numbo3-bot, Lightbot, Jarble, Greyhood, Luckas-bot, Yobot, Richigi, AnomieBOT, Citation bot, ArthurBot, LovesMacs, LilHelpa, Obersachsebot, Xqbot, RibotBOT, Steve Quinn, Bento00, Alph Bot, EmausBot, Solarra, Dcirovic, Hhhippo, NGPriest, Yamagawa10k, ClueBot NG, Manzzoku, Tylko, O.Koslowski, Helpful Pixie Bot, BG19bot, Altaïr, Neshmick, Fizped~enwiki, Alexbatroff, Jwoodward48wiki, Gjramayya, ECPL01 and Anonymous: 80 • Vacuum arc Source: http://en.wikipedia.org/wiki/Vacuum%20arc?oldid=642429562 Contributors: Heron, Glenn, Omegatron, Fvw, Wjbeaty, LucasVB, Jag123, Bert Hickman, BRW, Axeman89, BD2412, Shaddack, Petri Krohn, SmackBot, DMacks, Dogears, Ileresolu, Glrx, Sunyataburus, Citation bot, RGForbes, Citation bot 1, Bibcode Bot, Shawn Worthington Laser Plasma, Monkbot and Anonymous: 7 • Cathodic arc deposition Source: http://en.wikipedia.org/wiki/Cathodic%20arc%20deposition?oldid=657289719 Contributors: Rich Farmbrough, BD2412, Josh Parris, Mattopia, Tone, SmackBot, Salmar, Iepeulas, SiobhanHansa, R'n'B, Lantonov, Aanders, Vsilcox, EoGuy, SmoJoe, Sunyataburus, Don Mattox, Addbot, LaaknorBot, Legobot, Luckas-bot, Cepheiden, AtominoWIKI, BG19bot, ChrisGualtieri, Kyrsjo and Anonymous: 19 • Glow discharge Source: http://en.wikipedia.org/wiki/Glow%20discharge?oldid=650316535 Contributors: Ixfd64, Julesd, Glenn, Zoicon5, Omegatron, Alan Liefting, Art Carlson, Foobar, Eregli bob, Iantresman, Slike, RichardNeill, Atlant, BryanD, Wtshymanski, MZMcBride, Brighterorange, SanGatiche, Arnero, BradBeattie, CJLL Wright, YurikBot, Shaddack, Kkmurray, SmackBot, Redline, Georg-Johann, Dogears, Ohconfucius, Achem, Chetvorno, KerryVeenstra, CmdrObot, Matthew Proctor, Ileresolu, AntiVandalBot, Ccrrccrr, Photodude, Clivepollard, Outlook, Rettetast, Glrx, Reedy Bot, BagpipingScotsman, Daniele.tampieri, Steel1943, PNG crusade bot, TwilligToves, Mahogny, SieBot, ScAvenger lv, Moletrouser, Nergaal, Namazu-tron, Addbot, LaaknorBot, Mpfiz, Zorrobot, Luckas-bot, Zaereth, MinuxMa, Citation bot, Kyng, Tom.Reding, Teravolt, PowerLab net, EmausBot, WikitanvirBot, Stovl, ChemMater, MarcS222, Donner60, Huanhoon, Oddbodz, Helpful Pixie Bot, Shawn Worthington Laser Plasma, ChrisGualtieri, The Herald, ȸ and Anonymous: 34 • Fluorescent lamp Source: http://en.wikipedia.org/wiki/Fluorescent%20lamp?oldid=661732554 Contributors: AxelBoldt, Bryan Derksen, Malcolm Farmer, Rjstott, Lorax, Codeczero, Ray Van De Walker, Heron, Hephaestos, Frecklefoot, Edward, RTC, Delirium, Kosebamse, Ahoerstemeier, Ronz, Kragen, Glenn, Andres, Glueball, Smack, Tobyvoss, Mulad, Ec5618, Bemoeial, Reddi, Stone, Radiojon, Laussy, Maximus Rex, Taxman, Omegatron, David.Monniaux, Jeffq, Donarreiskoffer, Robbot, Ke4roh, Hankwang, Chealer, Chris 73, RedWolf, Academic Challenger, Sndrsn, Bkell, EvilPettingZoo, Jpo, Gwalla, DocWatson42, MPF, DavidCary, Art Carlson, Brona, Archenzo, Bobblewik, Edcolins, Neilc, Vadmium, Chowbok, Gadfium, Andycjp, Dan aka jack, H Padleckas, Icairns, Blue387, Iantresman, WpZurp, Kevin Rector, Deglr6328, Inkwina, Qui1che, Mormegil, JTN, Discospinster, Shinglor, YUL89YYZ, Bender235, Jaberwocky6669, Kbh3rd, Mattdm, Mcpusc, MBisanz, Wfisher, Evand, Dennis Brown, The Noodle Incident, West London Dweller, Bobo192, Snozzberry, Meggar, BrokenSegue, Rmv, Ygfperson, Joe Jarvis, Jhd, WideArc, Alansohn, Mgaved, Guy Harris, Atlant, Keenan Pepper, Andrew Gray, Sade, Nasukaren, Stevestrange, Stillnotelf, Miltonhowe, Wtshymanski, Shoefly, Vuo, H2g2bob, Skatebiker, Gene Nygaard, Cnsupplier, Kbolino, Kenyon, Shimeru, JimJim, Linas, Mindmatrix, Jpers36, Davidkazuhiro, Pol098, Slike2, Cbdorsett, Isnow, SDC, Zzyzx11, Crucis, Marudubshinki, BD2412, Reisio, Saperaud~enwiki, Rjwilmsi, Hitssquad, Hezery99, Mzhao, SMC, Snsh, Vegaswikian, Krash, Fred Bradstadt, GregAsche, Splarka, G Clark, UltraMako101, SiriusB, Nihiltres, Who, Gurch, A. Square, Lmatt, Srleffler, Milomedes, Bgwhite, Adoniscik, YurikBot, Ugha, Wavelength, Jamesmorrison, Huw Powell, H005, Midgley, RussBot, DMahalko, Hellbus, Gaius Cornelius, Shaddack, Rsrikanth05, Anomalocaris, David R. Ingham, Bvanderveen, Grafen, Gerben49~enwiki, CaliforniaAliBaba, Voidxor, Saberwyn, Bucketsofg, Bota47, Jeh, Daniel C, Light current, PTSE, Tabby, E Wing, Shawnc, Geoffrey.landis, SorryGuy, Nimbex, Whouk, Charlie Tango, Lunarsurface, Some guy, SmackBot, FocalPoint, Karlchwe, Derek Andrews, Herostratus, InverseHypercube, Thorseth, AndreasJS, Misto, Eskimbot, Nil Einne, Antifumo, Polaron, Chris the speller, Agateller, JesseStone, Oli Filth, EncMstr, Fluri, Analogue Kid, Adpete, Nbarth, Chendy, Dethme0w, Can't sleep, clown will eat me, Jacob Poon, OrphanBot, JonHarder, Xmastree, VMS Mosaic, Bassman2, Fuhghettaboutit, Jwy, LMF5000, Steve Hart, Dcamp314, DMacks, Jóna Þórunn, P373r, Dogears, DJIndica, Bige1977, The undertow, Anlace, John, Dwpaul, J 1982, Jaganath, Mgiganteus1, Peterlewis, Cielomobile, CoolKoon, Ckatz, Offby1, Soulkeeper, Slakr, Beetstra, Monni95, NJA, Peter Horn, JoeBot, Linkspamremover, Ziusudra, Rsteif, D'lin, Chetvorno, Vaughan Pratt, CRGreathouse, CmdrObot, Van helsing, Smile4ru, Cydebot, Peripitus, Kairotic, KarolS, Uniqueuponhim, Tawkerbot4, Punainen Nörtti, Andrewdmartin, Trev M, Saintrain, Ozguy89, Thijs!bot, Pajz, N5iln, Drmemory, Chris01720, Electron9, Thomprod, Mailseth, Nick Number, CarbonX, Pap3rw8, Dawnseeker2000, Enyc, RoboServien, Trengarasu, Mentifisto, AntiVandalBot, Majorly, Gioto, Saimhe, Guy Macon, Opelio, Gh5046, Kuteni, Res2216firestar, JAnDbot, WmRowan, 100DashSix, Easchiff, Magioladitis, Bongwarrior, VoABot II, Yandman, Appraiser, Tomhannen, Cableguyjim, Kevinmon, Gutzmer, SandStone, Thibbs, Spellmaster, Halogenated, DerHexer, JaGa, WLU, Pinokijo, Cheesebyproduct, Yobol, Hdt83, MartinBot, Schmloof, Quickmythril, Reguiieee, SmokeySteve, Glrx, CommonsDelinker, Pekaje, Gutta Percha, Johnibravo, J.delanoy, Mindgames11, Jesant13, Achuul8er, Metrax, PolychromePlatypus, Acalamari, Michael Daly, Katalaveno, PedEye1, Darkblast93, Afluegel, Mikael Häggström, Ephebi, ThomasNichols, Plasticup, NewEnglandYankee, Sparcules, Master shepherd, Johnnie ong, Cobi, Anatoly larkin, Atropos235, Remember the dot, Drablow, Funandtrvl, Lights, Uiew, CWii, TXiKiBoT, MilkTheImp, Shalom S., The Original Wildbear, Technopat, Hqb, Acjohns, Qxz, Qbert203, Whitepines, Piper8, Eubulides, Vladsinger, Andy Dingley, Cutemonkey77, Goldkills, Jpeeling, Buhin, Insanity Incarnate, Bitbut, C0N6R355, Bpdc 01, SieBot, Tresiden, TORQUENDB, Timothy Cooper, Yintan, Lumenteck, Steve19steve, Permacultura, Mickea, Carnun, Hiddenfromview, ‫ترجمان‬05, Macy, Ablamp, Anchor Link Bot, Tuntable, Leezahester, Dlrohrer2003, ClueBot, HujiBot, LP-mn, The Thing That Should Not Be, TinyMark, Techdawg667, EoGuy, Wysprgr2005, GreenSpigot, Mild Bill Hiccup, Uncle Milty, Sebokmike, Niceguyedc, Shjacks45, Drewster1829, Excirial, LifeofFred, 12 Noon, MorrisRob, LarryMorseDCOhio, Iohannes Animosus, Tnxman307, WWriter, Aprout, 7, Versus22, GrahamDo, Elizabeth.baer, SoxBot III, Ostinato2, Weckmansj, Ginbot86, Strix nihildom, DumZiBoT, XLinkBot, Mjharrison, Theultimatezone, TimeToSell, Little Mountain 5, NellieBly, Badgernet, JinJian, Alchaemist, TheMINT400, Addbot, Cantaloupe2, Freakmighty, DOI bot, Energyqueen, Shirtwaist, Favonian, Berkunt, Tide rolls, Lightbot, ‫דוד שי‬, TinaTimpton~enwiki, Lucacalciatore, DK4, Ben Ben, Legobot,

5.14. TEXT AND IMAGE SOURCES, CONTRIBUTORS, AND LICENSES

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Yobot, Zaereth, Themfromspace, Neotesla, Paraballo, A Stop at Willoughby, Amicon, AnomieBOT, BassmanIII, Kcgrant, Jim1138, Kingpin13, Mahmudmasri, Citation bot, Akilaa, Awinbisa, Sadrettin, Clark89, Quebec99, Jagcat98, Bluppen, Richard A Hall, Placidvortex, Capricorn42, Etoombs, Kidcharlemagne101, J04n, ELIOT2000, Letsgoridebikes, SPKirsch, Rainald62, Natural Cut, Krrish23, Mishka.medvezhonok, FrescoBot, Tobby72, Hobsonlane, RicHard-59, JuniperisCommunis, Idyllic press, HJ Mitchell, Citation bot 1, Chenopodiaceous, Pinethicket, I dream of horses, Adlerbot, Fosekfotos, Tom.Reding, Calmer Waters, Pegasus33, Jschnur, Mifsud26, Gigantor205, Symppis, IJBall, DrLit, Khaotika, Alexey Goral~enwiki, Tbhotch, Minimac, DARTH SIDIOUS 2, RjwilmsiBot, Dirtpoorwizard, Jackehammond, Nmartin1, Bamaslamma1003, Teravolt, Slon02, EmausBot, Energy Dome, John of Reading, Annunciation, Chastitywest, Bigbird900, GoingBatty, K6ka, Richardop3, Thecheesykid, Drewpoleon, Mz7, Aura Light UK, Selladour, Westley Turner, H3llBot, X bvansanten X, Юрий Столетов, Donner60, DASHBotAV, 28bot, Autisexp235, ClueBot NG, Gareth Griffith-Jones, Jenova20, Brendon12291, DieSwartzPunkt, Maverick kim, Castncoot, Widr, GlassLadyBug, Reify-tech, Amir Fatkullin, CasualVisitor, Shakir Ahmed73, Boggle987, Helpful Pixie Bot, Calabe1992, Wbm1058, Alavanca~enwiki, Nature4, Silvrous, CitationCleanerBot, Emanukel, Michaelkevinjackson, Cocacolaisbetterthanpepsi, BattyBot, Crankyfrank, ChrisGualtieri, Tagremover, Webclient101, 331dot, JRYon, BigMatow, Pravito, Djaiprakash naidu, Lewis Goudy, Lucas.wogernese, Monkbot, Kenji Higurashi, Cdot25, MEGUSTANADAAARR, Hetalia paris12, Croakobsidian, Lcso2015, ZackQB and Anonymous: 727

5.14.2

Images

• File:220V_plug_arc_damage.jpg Source: http://upload.wikimedia.org/wikipedia/commons/f/f9/220V_plug_arc_damage.jpg License: CC BY-SA 3.0 Contributors: Own work Original artist: Shaddack • File:65W_SRS_fluorescent_lamp_starting.OGG Source: http://upload.wikimedia.org/wikipedia/commons/9/95/65W_SRS_ fluorescent_lamp_starting.OGG License: Public domain Contributors: Own work Original artist: ELIOT2000 • File:AksenovQuaterTorusFilter.jpg Source: http://upload.wikimedia.org/wikipedia/commons/4/48/AksenovQuaterTorusFilter.jpg License: CC BY-SA 3.0 Contributors: Own work Original artist: Sunyataburus • File:AlCrTiN-CoatedHob_NanoShieldPVD_Thailand.jpg Source: http://upload.wikimedia.org/wikipedia/commons/6/65/ AlCrTiN-CoatedHob_NanoShieldPVD_Thailand.jpg License: CC BY-SA 3.0 Contributors: Own work Original artist: Sunyataburus • File:AlTiNCoatedEndmill_NanoShieldPVD_Thailand.JPG Source: http://upload.wikimedia.org/wikipedia/commons/1/1f/ AlTiNCoatedEndmill_NanoShieldPVD_Thailand.JPG License: CC BY-SA 3.0 Contributors: Own work Original artist: Sunyataburus • File:ArcSource_SablevType.jpg Source: http://upload.wikimedia.org/wikipedia/commons/e/e8/ArcSource_SablevType.jpg License: CC BY-SA 3.0 Contributors: Own work Original artist: Sunyataburus • File:Arcing_pickup_shoe.jpg Source: http://upload.wikimedia.org/wikipedia/commons/b/bf/Arcing_pickup_shoe.jpg License: Public domain Contributors: Own work Original artist: Taken by SPSmiler • File:CaOmelt1.jpg Source: http://upload.wikimedia.org/wikipedia/en/0/04/CaOmelt1.jpg License: PD Contributors: Own work Original artist: Skatebiker (talk) (Uploads) • File:Commons-logo.svg Source: http://upload.wikimedia.org/wikipedia/en/4/4a/Commons-logo.svg License: ? Contributors: ? Original artist: ? • File:Compact_fluorescent_straight_crop.jpg Source: http://upload.wikimedia.org/wikipedia/commons/2/22/Compact_fluorescent_ straight_crop.jpg License: CC0 Contributors: Compact fluorescent straight.jpg Original artist: Nroose • File:EL_2x58ngn.jpg Source: http://upload.wikimedia.org/wikipedia/commons/7/7f/EL_2x58ngn.jpg License: CC BY-SA 3.0 Contributors: Own work Original artist: Symppis • File:Early_Cooper_Hewitt_mercury_vapor_lamp.jpg Source: http://upload.wikimedia.org/wikipedia/commons/d/d1/Early_Cooper_ Hewitt_mercury_vapor_lamp.jpg License: Public domain Contributors: Downloaded July 27, 2013 from Ray Stannard Baker 1903 Boys’ Second Book of Inventions, McClure, Phillips and Co., New York, p. 305 on Google Books Original artist: Unknown • File:Electric_arc.jpg Source: http://upload.wikimedia.org/wikipedia/commons/7/7a/Electric_arc.jpg License: Public domain Contributors: Own work Original artist: Khimich Alex • File:Electric_glow_discharge_schematic.png Source: http://upload.wikimedia.org/wikipedia/commons/2/2b/Electric_glow_ discharge_schematic.png License: CC BY 2.5 Contributors: http://en.wikipedia.org/wiki/File:Electric_glow_discharge_schematic.png Original artist: http://en.wikipedia.org/wiki/User:Iantresman • File:Fluorescent-lamp-electronic-ballast.webm Source: http://upload.wikimedia.org/wikipedia/commons/7/76/ Fluorescent-lamp-electronic-ballast.webm License: CC BY-SA 3.0 Contributors: Own work Original artist: Rmv • File:Fluorescent_Black-Light_spectrum_with_peaks_labelled.gif Source: http://upload.wikimedia.org/wikipedia/commons/0/0a/ Fluorescent_Black-Light_spectrum_with_peaks_labelled.gif License: Public domain Contributors: ? Original artist: ? • File:Fluorescent_Energy.svg Source: http://upload.wikimedia.org/wikipedia/en/c/c8/Fluorescent_Energy.svg License: CC-BY-SA-3.0 Contributors: I (Wtshymanski (talk)) created this work entirely by myself. Original artist: Wtshymanski (talk) • File:Fluorescent_Lamp_Inverter.png Source: http://upload.wikimedia.org/wikipedia/commons/6/6c/Fluorescent_Lamp_Inverter.png License: CC-BY-SA-3.0 Contributors: Own work Original artist: Neotesla • File:Fluorescent_Light.svg Source: http://upload.wikimedia.org/wikipedia/commons/e/e1/Fluorescent_Light.svg License: Public domain Contributors: Own work Original artist: Inkwina (talk · contribs) • File:Fluorescent_beat_effect.ogv Source: http://upload.wikimedia.org/wikipedia/commons/3/30/Fluorescent_beat_effect.ogv License: CC BY-SA 3.0 Contributors: Own work Original artist: Alexey Goral

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CHAPTER 5. FLUORESCENT LAMP

• File:Fluorescent_lamp-electronic_ballast_starter-movie_VNr°0001.ogv Source: http://upload.wikimedia.org/wikipedia/commons/b/ b5/Fluorescent_lamp-electronic_ballast_starter-movie_VNr%C2%B00001.ogv License: CC BY-SA 3.0 at Contributors: Own work Original artist: D-Kuru • File:Fluorescent_lamp_hold_for_T8_and_T12_lamps.jpg Fluorescent_lamp_hold_for_T8_and_T12_lamps.jpg License: Brown

Source: http://upload.wikimedia.org/wikipedia/commons/0/06/ CC BY-SA 3.0 Contributors: Own work Original artist: Dennis

• File:Fluorescent_lamp_spectrum.jpg Source: http://upload.wikimedia.org/wikipedia/commons/f/f5/Fluorescent_lamp_spectrum.jpg License: Public domain Contributors: Own work Original artist: Reguiieee (talk) • File:Fluorescent_lamps_artistic.jpg Source: http://upload.wikimedia.org/wikipedia/commons/5/51/Fluorescent_lamps_artistic.jpg License: CC BY 2.0 Contributors: Flickr Original artist: This image was originally posted to Flickr by OiMax at http://flickr.com/photos/ [email protected]/404614118. It was reviewed on 20 May 2007 by the FlickreviewR robot and was confirmed to be licensed under the terms of the cc-by-2.0. • File:Fluorescent_lighting_spectrum_peaks_labelled.svg Source: http://upload.wikimedia.org/wikipedia/commons/8/8d/Fluorescent_ lighting_spectrum_peaks_labelled.svg License: CC-BY-SA-3.0 Contributors: • Fluorescent_lighting_spectrum_peaks_labelled.png Original artist: Fluorescent_lighting_spectrum_peaks_labelled.png: en:user:Deglr6328 • File:Fluorescent_tube_under_electric_line.jpg Source: http://upload.wikimedia.org/wikipedia/commons/b/bb/Fluorescent_tube_ under_electric_line.jpg License: CC BY-SA 3.0 Contributors: Own work Original artist: user:BaronAlaric BaronAlaric • File:Fluorescentfixturebelow20806.JPG Source: http://upload.wikimedia.org/wikipedia/en/a/a7/Fluorescentfixturebelow20806.JPG License: PD Contributors: ? Original artist: ? • File:Folder_Hexagonal_Icon.svg Source: http://upload.wikimedia.org/wikipedia/en/4/48/Folder_Hexagonal_Icon.svg License: Cc-bysa-3.0 Contributors: ? Original artist: ? • File:Germicidal_Lamp_2.jpg Source: http://upload.wikimedia.org/wikipedia/commons/7/75/Germicidal_Lamp_2.jpg License: CC BY-SA 2.5 Contributors: Own work Original artist: Atlant • File:Germicidal_UV_discharge_tube_glow.jpg Source: http://upload.wikimedia.org/wikipedia/commons/8/8e/Germicidal_UV_ discharge_tube_glow.jpg License: CC-BY-SA-3.0 Contributors: Own work Original artist: Deglr6328 • File:Glow_discharge_current-voltage_curve_vertical.svg Source: http://upload.wikimedia.org/wikipedia/commons/4/4e/Glow_ discharge_current-voltage_curve_vertical.svg License: CC BY-SA 3.0 Contributors: • Derivative of GlowDischargeVoltAmpere.jpg. Original artist: • Original work: Wikigian • File:Helical_fluorescent_lamp_spectrum_by_diffraction_grating.JPG Source: http://upload.wikimedia.org/wikipedia/commons/2/ 22/Helical_fluorescent_lamp_spectrum_by_diffraction_grating.JPG License: CC BY-SA 4.0 Contributors: Own work Original artist: Zaereth • File:Helical_fluorescent_lamp_thermal_image.jpg Source: http://upload.wikimedia.org/wikipedia/commons/1/13/Helical_ fluorescent_lamp_thermal_image.jpg License: CC0 Contributors: Own work Original artist: Zaereth • File:Kelvin_Temperature_Chart.svg Source: http://upload.wikimedia.org/wikipedia/commons/c/cc/Kelvin_Temperature_Chart.svg License: CC BY-SA 3.0 Contributors: • Kelvin_Temperature_Chart.jpg Original artist: Kelvin_Temperature_Chart.jpg: Mifsud26 • File:LAjaHID.jpg Source: http://upload.wikimedia.org/wikipedia/commons/8/80/LAjaHID.jpg License: CC BY 3.0 Contributors: Own work Original artist: Symppis • File:Leuchtstofflampen-chtaube050409.jpg Source: http://upload.wikimedia.org/wikipedia/commons/5/5b/ Leuchtstofflampen-chtaube050409.jpg License: CC BY-SA 2.0 de Contributors: Own work Original artist: Created by Christian Taube, white balance fixed by Deglr6328 • File:Lichtbogen_3000_Volt.jpg Source: http://upload.wikimedia.org/wikipedia/commons/f/f8/Lichtbogen_3000_Volt.jpg License: CC BY 3.0 Contributors: Own work Original artist: Achim Grochowski -- Achgro • File:Lightning_NOAA.jpg Source: http://upload.wikimedia.org/wikipedia/commons/7/7d/Lightning_NOAA.jpg License: Public domain Contributors: NOAA Photo Library (direct), NOAA Central Library; OAR/ERL/National Severe Storms Laboratory (NSSL), Image ID: nssl0010 Original artist: C. Clark • File:Magnetek_Watt_Reducer_HPF_Rapid_Start_Ballast.jpg Source: http://upload.wikimedia.org/wikipedia/commons/7/ 72/Magnetek_Watt_Reducer_HPF_Rapid_Start_Ballast.jpg License: Public domain Contributors: Own work Original artist: Bamaslamma1003 • File:Neon_lamp_on_DC.JPG Source: http://upload.wikimedia.org/wikipedia/commons/2/2c/Neon_lamp_on_DC.JPG License: CC BY-SA 3.0 Contributors: • Derivative of Neonlamp3.JPG Original artist: • Original work: Ceinturion • File:New_GE_Ballast.JPG Source: http://upload.wikimedia.org/wikipedia/commons/0/0a/New_GE_Ballast.JPG License: Public domain Contributors: Own work Original artist: Dmitry G • File:Old_USSR_Ballast.JPG Source: http://upload.wikimedia.org/wikipedia/commons/c/c6/Old_USSR_Ballast.JPG License: Public domain Contributors: Own work (Own photo) Original artist: Dmitry G • File:People_icon.svg Source: http://upload.wikimedia.org/wikipedia/commons/3/37/People_icon.svg License: CC0 Contributors: OpenClipart Original artist: OpenClipart

5.14. TEXT AND IMAGE SOURCES, CONTRIBUTORS, AND LICENSES

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